铝表面的冰核性质

IF 3.2 3区 化学 Q2 CHEMISTRY, PHYSICAL
Carlotta E. A. Blamey-Beccaria, Michael A. Parkes, Jinjie Li and Christoph G. Salzmann*, 
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引用次数: 0

摘要

过冷水滴成核在航空、电力传输、航运、太空飞行等多个技术领域发挥着关键作用。尽管它很重要,但水在表面冻结的基本机制仍然知之甚少。在这项研究中,我们研究了几种铝合金(1050、5083、5251、6060和6082)的过冷液滴的冻结行为。我们的研究结果表明,所有铝表面都表现出适度的冰核能力。高水平的表面氧化和镁含量导致更高的平均冰核温度,粗糙的表面通常比抛光的表面更有效地促进冰的形成。一个例外是刚打磨过的1050合金,这是我们研究过的最柔软、最纯净的铝,它的微米尺度的“坑”特征似乎引发了冰核。表面时效后,5251合金的冰核能力最强,6082合金的冰核能力最低。总的来说,我们的研究结果强调了在减少铝表面结冰时考虑表面粗糙度、特定缺陷和合金成分之间相互作用的重要性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Ice Nucleation Properties of Aluminum Surfaces

The nucleation of ice from supercooled water droplets plays a critical role across various technological sectors including aviation, power transmission, shipping, and space flight. Despite its importance, the fundamental mechanisms of water freezing on surfaces remain poorly understood. In this study, we investigate the freezing behavior of supercooled droplets on several aluminum alloys (1050, 5083, 5251, 6060, and 6082) using our custom-designed IceBox instrument. Our findings show that all aluminum surfaces exhibit moderate ice-nucleating capabilities. High levels of surface oxidation and magnesium content lead to higher average ice-nucleation temperatures, and rough surfaces generally promote ice formation more effectively than polished ones. An exception is the freshly polished 1050 alloy, the softest and purest aluminum examined, where micrometer-scale “pit” features appear to initiate ice nucleation. After surface aging, the 5251 alloy displays the highest ice-nucleating ability, while the 6082 alloy shows the lowest. Overall, our results highlight the importance of considering the interplay between surface roughness, specific defects, and alloy composition when aiming to reduce ice formation on aluminum surfaces.

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来源期刊
The Journal of Physical Chemistry C
The Journal of Physical Chemistry C 化学-材料科学:综合
CiteScore
6.50
自引率
8.10%
发文量
2047
审稿时长
1.8 months
期刊介绍: The Journal of Physical Chemistry A/B/C is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.
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