{"title":"具有频散的阻塞扩散Warburg阻抗的扩散响应特征频率","authors":"Samuel Cruz-Manzo","doi":"10.1016/j.fub.2025.100084","DOIUrl":null,"url":null,"abstract":"<div><div>The blocked-diffusion Warburg impedance with frequency dispersion (BDWf) can be considered in equivalent electrical circuits to characterise the low-frequency impedance response of batteries. In this study, the characteristic frequency of the diffusion response <span><math><msub><mrow><mi>f</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> of the BDWf impedance is calculated using the analytical transfer function reported in a previous study and the Newton-Raphson iteration method. The results show that the characteristic frequency of the diffusion response <span><math><msub><mrow><mi>f</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> is a numerical value x (calculated from the Newton-Raphson iteration) greater than the frequency calculated from the time constant <span><math><msub><mrow><mi>τ</mi></mrow><mrow><mi>BW</mi></mrow></msub></math></span> of the BDWf impedance as follows: <span><math><mrow><msub><mrow><mi>f</mi></mrow><mrow><mi>d</mi></mrow></msub><mo>=</mo><mfrac><mrow><mi>x</mi></mrow><mrow><mn>2</mn><mi>π</mi><msub><mrow><mi>τ</mi></mrow><mrow><mi>BW</mi></mrow></msub></mrow></mfrac></mrow></math></span>. In this study, the characteristic frequency of the diffusion response <span><math><msub><mrow><mi>f</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> is also represented in the impedance response of the BDWf impedance. The characteristic diffusion time constant <span><math><msub><mrow><mi>τ</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> calculated from the characteristic frequency of the diffusion response <span><math><msub><mrow><mi>f</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> of the BDWf impedance and estimated from battery impedance measurements, could provide a new estimation of the effective anomalous diffusion coefficient of charge carriers in battery electrodes with heterogeneous particle structure. Additionally, the output voltage of a battery measured at the characteristic diffusion time constant <span><math><msub><mrow><mi>τ</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> during current pulse tests could be considered a valuable ageing signature for assessing the state of health of the battery.</div></div>","PeriodicalId":100560,"journal":{"name":"Future Batteries","volume":"6 ","pages":"Article 100084"},"PeriodicalIF":0.0000,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Characteristic frequency of the diffusion response of the blocked-diffusion Warburg impedance with frequency dispersion\",\"authors\":\"Samuel Cruz-Manzo\",\"doi\":\"10.1016/j.fub.2025.100084\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The blocked-diffusion Warburg impedance with frequency dispersion (BDWf) can be considered in equivalent electrical circuits to characterise the low-frequency impedance response of batteries. In this study, the characteristic frequency of the diffusion response <span><math><msub><mrow><mi>f</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> of the BDWf impedance is calculated using the analytical transfer function reported in a previous study and the Newton-Raphson iteration method. The results show that the characteristic frequency of the diffusion response <span><math><msub><mrow><mi>f</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> is a numerical value x (calculated from the Newton-Raphson iteration) greater than the frequency calculated from the time constant <span><math><msub><mrow><mi>τ</mi></mrow><mrow><mi>BW</mi></mrow></msub></math></span> of the BDWf impedance as follows: <span><math><mrow><msub><mrow><mi>f</mi></mrow><mrow><mi>d</mi></mrow></msub><mo>=</mo><mfrac><mrow><mi>x</mi></mrow><mrow><mn>2</mn><mi>π</mi><msub><mrow><mi>τ</mi></mrow><mrow><mi>BW</mi></mrow></msub></mrow></mfrac></mrow></math></span>. In this study, the characteristic frequency of the diffusion response <span><math><msub><mrow><mi>f</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> is also represented in the impedance response of the BDWf impedance. The characteristic diffusion time constant <span><math><msub><mrow><mi>τ</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> calculated from the characteristic frequency of the diffusion response <span><math><msub><mrow><mi>f</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> of the BDWf impedance and estimated from battery impedance measurements, could provide a new estimation of the effective anomalous diffusion coefficient of charge carriers in battery electrodes with heterogeneous particle structure. Additionally, the output voltage of a battery measured at the characteristic diffusion time constant <span><math><msub><mrow><mi>τ</mi></mrow><mrow><mi>d</mi></mrow></msub></math></span> during current pulse tests could be considered a valuable ageing signature for assessing the state of health of the battery.</div></div>\",\"PeriodicalId\":100560,\"journal\":{\"name\":\"Future Batteries\",\"volume\":\"6 \",\"pages\":\"Article 100084\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Future Batteries\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2950264025000632\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Future Batteries","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2950264025000632","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Characteristic frequency of the diffusion response of the blocked-diffusion Warburg impedance with frequency dispersion
The blocked-diffusion Warburg impedance with frequency dispersion (BDWf) can be considered in equivalent electrical circuits to characterise the low-frequency impedance response of batteries. In this study, the characteristic frequency of the diffusion response of the BDWf impedance is calculated using the analytical transfer function reported in a previous study and the Newton-Raphson iteration method. The results show that the characteristic frequency of the diffusion response is a numerical value x (calculated from the Newton-Raphson iteration) greater than the frequency calculated from the time constant of the BDWf impedance as follows: . In this study, the characteristic frequency of the diffusion response is also represented in the impedance response of the BDWf impedance. The characteristic diffusion time constant calculated from the characteristic frequency of the diffusion response of the BDWf impedance and estimated from battery impedance measurements, could provide a new estimation of the effective anomalous diffusion coefficient of charge carriers in battery electrodes with heterogeneous particle structure. Additionally, the output voltage of a battery measured at the characteristic diffusion time constant during current pulse tests could be considered a valuable ageing signature for assessing the state of health of the battery.