{"title":"稀土氧化物的光学和介电性质的太赫兹时域光谱定量分析","authors":"Tong Zhang , Zhiyuan Zheng , Mingrui Zhang , Chutong Gao , Shanshan Li , Haochong Huang , Qiming Qiu , Zili Zhang , Kunfeng Qiu","doi":"10.1016/j.jmrt.2025.06.059","DOIUrl":null,"url":null,"abstract":"<div><div>The insight into the optical and dielectric properties of rare earth elements is critical for industrial development. A method to quantitatively analyse binary rare earth oxide mixtures is proposed based on terahertz time-domain spectroscopy. The terahertz refractive index is extracted by Complex Refractive Index model and the real permittivity of the samples is processed by Landau-Lifshitz-Looyenga model for mixtures of rare earth oxides at different volume ratios, respectively. Application of effective medium theory to raw data from single component samples to eliminate the dielectric influence of dilute PTFE matrices and captured air voids. Efficient extraction of intrinsic refractive index and real permittivity will facilitate quantitative characterization and application of rare earth oxides. This provides a new method to insight the optical properties and dielectric properties of rare earth elements in terahertz frequency band.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"37 ","pages":"Pages 912-920"},"PeriodicalIF":6.6000,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Quantitative analysis of optical and dielectric properties of rare earth oxides by terahertz time-domain spectroscopy\",\"authors\":\"Tong Zhang , Zhiyuan Zheng , Mingrui Zhang , Chutong Gao , Shanshan Li , Haochong Huang , Qiming Qiu , Zili Zhang , Kunfeng Qiu\",\"doi\":\"10.1016/j.jmrt.2025.06.059\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The insight into the optical and dielectric properties of rare earth elements is critical for industrial development. A method to quantitatively analyse binary rare earth oxide mixtures is proposed based on terahertz time-domain spectroscopy. The terahertz refractive index is extracted by Complex Refractive Index model and the real permittivity of the samples is processed by Landau-Lifshitz-Looyenga model for mixtures of rare earth oxides at different volume ratios, respectively. Application of effective medium theory to raw data from single component samples to eliminate the dielectric influence of dilute PTFE matrices and captured air voids. Efficient extraction of intrinsic refractive index and real permittivity will facilitate quantitative characterization and application of rare earth oxides. This provides a new method to insight the optical properties and dielectric properties of rare earth elements in terahertz frequency band.</div></div>\",\"PeriodicalId\":54332,\"journal\":{\"name\":\"Journal of Materials Research and Technology-Jmr&t\",\"volume\":\"37 \",\"pages\":\"Pages 912-920\"},\"PeriodicalIF\":6.6000,\"publicationDate\":\"2025-06-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Research and Technology-Jmr&t\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2238785425014814\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Research and Technology-Jmr&t","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2238785425014814","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Quantitative analysis of optical and dielectric properties of rare earth oxides by terahertz time-domain spectroscopy
The insight into the optical and dielectric properties of rare earth elements is critical for industrial development. A method to quantitatively analyse binary rare earth oxide mixtures is proposed based on terahertz time-domain spectroscopy. The terahertz refractive index is extracted by Complex Refractive Index model and the real permittivity of the samples is processed by Landau-Lifshitz-Looyenga model for mixtures of rare earth oxides at different volume ratios, respectively. Application of effective medium theory to raw data from single component samples to eliminate the dielectric influence of dilute PTFE matrices and captured air voids. Efficient extraction of intrinsic refractive index and real permittivity will facilitate quantitative characterization and application of rare earth oxides. This provides a new method to insight the optical properties and dielectric properties of rare earth elements in terahertz frequency band.
期刊介绍:
The Journal of Materials Research and Technology is a publication of ABM - Brazilian Metallurgical, Materials and Mining Association - and publishes four issues per year also with a free version online (www.jmrt.com.br). The journal provides an international medium for the publication of theoretical and experimental studies related to Metallurgy, Materials and Minerals research and technology. Appropriate submissions to the Journal of Materials Research and Technology should include scientific and/or engineering factors which affect processes and products in the Metallurgy, Materials and Mining areas.