{"title":"国际清算银行[5 - (anthracen-9-ylmeth-yl) 1、5、9-tri-aza-cyclododecan-1-ium] tetra-chlorido-zincate。","authors":"Yoshimi Ichimaru, Koichi Kato, Wanchun Jin, Masaaki Kurihara, Hiromasa Kurosaki","doi":"10.1107/S2414314625003566","DOIUrl":null,"url":null,"abstract":"<p><p>A crystalline salt comprising two monoprotonated polyamine ligands and one tetra-chloro-zincate(II) anion was prepared, (C<sub>24</sub>H<sub>32</sub>N<sub>3</sub>)<sub>2</sub>[ZnCl<sub>4</sub>], and its crystal structure was analyzed and compared with those of structurally related compounds bearing different macrocyclic frameworks and pendant arms. The protonated nitro-gen atoms engaged in intra-molecular hydrogen bonding with other nitro-gen atoms within the macrocyclic ring. In the crystal, the pendant anthracene groups participated in inter-molecular π-π and C-H⋯π inter-actions, contributing to crystal cohesion.</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 Pt 5","pages":"x250356"},"PeriodicalIF":0.0000,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12142395/pdf/","citationCount":"0","resultStr":"{\"title\":\"Bis[5-(anthracen-9-ylmeth-yl)-1,5,9-tri-aza-cyclododecan-1-ium] tetra-chlorido-zincate.\",\"authors\":\"Yoshimi Ichimaru, Koichi Kato, Wanchun Jin, Masaaki Kurihara, Hiromasa Kurosaki\",\"doi\":\"10.1107/S2414314625003566\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>A crystalline salt comprising two monoprotonated polyamine ligands and one tetra-chloro-zincate(II) anion was prepared, (C<sub>24</sub>H<sub>32</sub>N<sub>3</sub>)<sub>2</sub>[ZnCl<sub>4</sub>], and its crystal structure was analyzed and compared with those of structurally related compounds bearing different macrocyclic frameworks and pendant arms. The protonated nitro-gen atoms engaged in intra-molecular hydrogen bonding with other nitro-gen atoms within the macrocyclic ring. In the crystal, the pendant anthracene groups participated in inter-molecular π-π and C-H⋯π inter-actions, contributing to crystal cohesion.</p>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"10 Pt 5\",\"pages\":\"x250356\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-05-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12142395/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1107/S2414314625003566\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/5/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314625003566","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/5/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
A crystalline salt comprising two monoprotonated polyamine ligands and one tetra-chloro-zincate(II) anion was prepared, (C24H32N3)2[ZnCl4], and its crystal structure was analyzed and compared with those of structurally related compounds bearing different macrocyclic frameworks and pendant arms. The protonated nitro-gen atoms engaged in intra-molecular hydrogen bonding with other nitro-gen atoms within the macrocyclic ring. In the crystal, the pendant anthracene groups participated in inter-molecular π-π and C-H⋯π inter-actions, contributing to crystal cohesion.
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