1,1′-[氧双（乙烷-2,1-二基）]双-（2-甲基磺胺基- 1h -苯并咪唑）的合成、晶体结构和Hirshfeld表面分析。

IF 0.6 Q4 CRYSTALLOGRAPHY

Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2025-06-01 DOI:10.1107/S2056989025003809

Ahmed Moussaif , Lhoussaine El Ghayati , Camille Kalonji Mubengayi , Abdulsalam Alsubari , El Mokhtar Essassi , Joel T. Mague , Youssef Ramli

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引用次数: 0

摘要

标题化合物C20H22N4OS2的不对称单元由两个独立的分子组成，其中一个是无序的。在每个分子中，末端苯并咪唑基团的平均平面彼此倾斜约68°。在晶体中，四分子链由C-H⋯N氢键和C-H⋯π（环）相互作用产生，并由C-H⋯π（环）和π-堆叠相互作用连接。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole)

In the title compound, the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetramolecular strands are generated by C—H⋯N hydrogen bonds and C—H⋯π(ring) interactions and are linked by C—H⋯π(ring) and π-stacking interactions.

The asymmetric unit of the title compound, C₂₀H₂₂N₄OS₂, consists of two independent molecules, one of which is disordered. In each molecule, the mean planes of the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetramolecular strands are generated by C—H⋯N hydrogen bonds and C—H⋯π(ring) interactions and are linked by C—H⋯π(ring) and π-stacking interactions.

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来源期刊

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.