1′，4′-二苯基-1a，1′，4′，4′，5′，9b-六氢-2′-h -二螺-[环丙[1]菲-1,2′-[1,4]对氧萘-3′，3′-噻吩]的合成与结构

IF 0.5 Q4 CRYSTALLOGRAPHY

Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2025-05-13 eCollection Date: 2025-06-01 DOI:10.1107/S2056989025004104

Yuewei Wen, Dasan M Thamattoor

引用次数: 0

摘要

标题化合物C39H30OS是在1,3-二苯基-异苯呋喃和3-（1a，9b-二氢- 1h -环丙[1]菲-1-基二烯）四氢噻吩之间无意中制备的Diels-Alder加合物。在这种高度拥挤的多环化合物的单一分子结构中，融合环、桥接环和螺旋环系统的组合都具有其特点。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Synthesis and structure of 1',4'-diphenyl-1a,1',4',4'',5'',9b-hexa-hydro-2''H-di-spiro-[cyclopropa[l]phenanthrene-1,2'-[1,4]ep-oxy-naphthalene-3',3''-thio-phene].

The title compound, C₃₉H₃₀OS, was inadvertently prepared as a Diels-Alder adduct between 1,3-di-phenyl-isobenzo-furan and 3-(1a,9b-di-hydro-1H-cyclo-propa[l]phenanthren-1-yl-idene)tetra-hydro-thio-phene. A combination of fused, bridged, and spiro-cyclic ring systems are all featured within a single mol-ecular structure of this highly crowded polycyclic compound.

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来源期刊

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.