模块化环戊烯环

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-05-28 DOI:10.1021/acs.orglett.5c0175010.1021/acs.orglett.5c01750

Adrian E. Samkian, Kasam Poonswat, Scott C. Virgil and Brian M. Stoltz*,

引用次数: 0

摘要

我们报道了丙炔锌试剂、不饱和1,3-二羰基和亲电试剂之间的模块化三组分环，以实现高取代环戊烯的快速构建。除了优化研究外，还研究了一系列底物。这些产品可以很容易地多样化，以突出其合成效用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A Modular Cyclopentene Annulation

查看原文本刊更多论文

A Modular Cyclopentene Annulation

We report a modular three-component annulation among propargyl zinc reagents, unsaturated 1,3-dicarbonyls, and electrophiles to enable rapid construction of highly substituted cyclopentenes. In addition to optimization studies, a range of substrates were investigated. These products can be readily diversified to highlight their synthetic utility.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.