{"title":"空间和地面条件下难熔Zr57V43合金共晶生长动力学及显微力学性能","authors":"Haipeng Wang, Haozhe Li, Chenhui Zheng, Liang Hu, Bingbo Wei","doi":"10.1016/j.actamat.2025.121213","DOIUrl":null,"url":null,"abstract":"<div><div>The eutectic growth kinetics and solidified microstructures of liquid Zr<sub>57</sub>V<sub>43</sub> refractory alloy were explored aboard the China Space Station (CSS), where long-term microgravity state and confined fluid flow were ensured synchronously. The thermophysical properties were determined at both metastable undercooled liquid and high temperature solid states, which were hard to measure accurately on the ground. The solidified microstructures exhibited eutectic cells with a novel ripple-like characteristic under the effects of 10<sup>–</sup><sup>5</sup> <em>g</em><sub>0</sub> microgravity and 73 K undercooling. The eutectic growth velocity attained 4.59 mm·s<sup>–</sup><sup>1</sup> in this case. The ripple-like pattern was formed by the (Zr) and V<sub>2</sub>Zr phases developing alternatively from the surface towards the droplet center, resulting from suppressed convection around the nucleation sites. Anomalous eutectic was distributed inside the eutectic cells and the lamellar eutectic outside due to the eutectic growth kinetics change. The anomalous eutectic and finer lamellar eutectic respectively lead to an 11.7 % and 13.2 % increase in micro-indentation hardness of the Zr<sub>57</sub>V<sub>43</sub> alloy compared with the levitationally solidified alloy at a similar undercooling on the ground. The research findings contribute to further understanding of novel microstructure formation and the performance change of eutectic alloys solidified in outer space.</div></div>","PeriodicalId":238,"journal":{"name":"Acta Materialia","volume":"295 ","pages":"Article 121213"},"PeriodicalIF":8.3000,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Eutectic growth kinetics and microscopic mechanical property of refractory Zr57V43 alloy under space and ground conditions\",\"authors\":\"Haipeng Wang, Haozhe Li, Chenhui Zheng, Liang Hu, Bingbo Wei\",\"doi\":\"10.1016/j.actamat.2025.121213\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The eutectic growth kinetics and solidified microstructures of liquid Zr<sub>57</sub>V<sub>43</sub> refractory alloy were explored aboard the China Space Station (CSS), where long-term microgravity state and confined fluid flow were ensured synchronously. The thermophysical properties were determined at both metastable undercooled liquid and high temperature solid states, which were hard to measure accurately on the ground. The solidified microstructures exhibited eutectic cells with a novel ripple-like characteristic under the effects of 10<sup>–</sup><sup>5</sup> <em>g</em><sub>0</sub> microgravity and 73 K undercooling. The eutectic growth velocity attained 4.59 mm·s<sup>–</sup><sup>1</sup> in this case. The ripple-like pattern was formed by the (Zr) and V<sub>2</sub>Zr phases developing alternatively from the surface towards the droplet center, resulting from suppressed convection around the nucleation sites. Anomalous eutectic was distributed inside the eutectic cells and the lamellar eutectic outside due to the eutectic growth kinetics change. The anomalous eutectic and finer lamellar eutectic respectively lead to an 11.7 % and 13.2 % increase in micro-indentation hardness of the Zr<sub>57</sub>V<sub>43</sub> alloy compared with the levitationally solidified alloy at a similar undercooling on the ground. The research findings contribute to further understanding of novel microstructure formation and the performance change of eutectic alloys solidified in outer space.</div></div>\",\"PeriodicalId\":238,\"journal\":{\"name\":\"Acta Materialia\",\"volume\":\"295 \",\"pages\":\"Article 121213\"},\"PeriodicalIF\":8.3000,\"publicationDate\":\"2025-06-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Materialia\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1359645425005002\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Materialia","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1359645425005002","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Eutectic growth kinetics and microscopic mechanical property of refractory Zr57V43 alloy under space and ground conditions
The eutectic growth kinetics and solidified microstructures of liquid Zr57V43 refractory alloy were explored aboard the China Space Station (CSS), where long-term microgravity state and confined fluid flow were ensured synchronously. The thermophysical properties were determined at both metastable undercooled liquid and high temperature solid states, which were hard to measure accurately on the ground. The solidified microstructures exhibited eutectic cells with a novel ripple-like characteristic under the effects of 10–5g0 microgravity and 73 K undercooling. The eutectic growth velocity attained 4.59 mm·s–1 in this case. The ripple-like pattern was formed by the (Zr) and V2Zr phases developing alternatively from the surface towards the droplet center, resulting from suppressed convection around the nucleation sites. Anomalous eutectic was distributed inside the eutectic cells and the lamellar eutectic outside due to the eutectic growth kinetics change. The anomalous eutectic and finer lamellar eutectic respectively lead to an 11.7 % and 13.2 % increase in micro-indentation hardness of the Zr57V43 alloy compared with the levitationally solidified alloy at a similar undercooling on the ground. The research findings contribute to further understanding of novel microstructure formation and the performance change of eutectic alloys solidified in outer space.
期刊介绍:
Acta Materialia serves as a platform for publishing full-length, original papers and commissioned overviews that contribute to a profound understanding of the correlation between the processing, structure, and properties of inorganic materials. The journal seeks papers with high impact potential or those that significantly propel the field forward. The scope includes the atomic and molecular arrangements, chemical and electronic structures, and microstructure of materials, focusing on their mechanical or functional behavior across all length scales, including nanostructures.