Supriyo Majumder, Raj Kumar Das, Chanchal Samanta, Chiranjeevi Thota and Bharat L. Newalkar
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Hydrogenation of CO2 into formate using an iridium catalyst containing proton-responsive imidazoline–amide ligands†
A series of air-stable, water-soluble iridium catalysts featuring imidazoline–amide ligands have been developed for the aqueous-phase hydrogenation of CO2 to formate, achieving a TON of 58 530. Notably, the ImA-1 catalyst also efficiently produces formate from bicarbonate. Moreover, this proton-responsive catalyst enables integrated CO2 capture with aqueous amines and its conversion to formate in the presence of H2, with a TON of 23 077.
期刊介绍:
A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis.
Editor-in-chief: Bert Weckhuysen
Impact factor: 5.0
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