S. Natrajan , K.K. Marhas , V.J. Rajesh , A. Mitra
{"title":"通过不溶性有机物的光谱研究对CM母体的热时间约束","authors":"S. Natrajan , K.K. Marhas , V.J. Rajesh , A. Mitra","doi":"10.1016/j.chemgeo.2025.122880","DOIUrl":null,"url":null,"abstract":"<div><div>A comprehensive study was conducted using Fourier Transform Infra-Red spectroscopy and Raman spectroscopy on chemically isolated insoluble organic matter from sixteen different carbonaceous chondrites (CI, CM) to understand the alteration duration and temperature relationships within CM- CI like bodies. The average temperatures based on disordered components of Raman spectra (T<sub>IOM</sub>), range from ~35 °C to 90 °C which are consistent with previously reported estimates. Using the established kinetic parameters based on insoluble organic matter, this study presents a novel approach to estimate duration of alteration in the CM parent body. An attempt is made to link the origin of the CM suite of samples from this study using the correlation between duration of alteration and parent body size as suggested by previous hydrothermal models. The majority of our samples fall into the category of multiple cloned small planetesimals or were part of an aggregate of these bodies (rubble pile). Infrared and Raman characteristics of Ryugu studies supports the correlation between parent body size, temperature, and the duration of alteration identified in our research. Additionally, we observe that the alteration of organic matter is regulated by the temperature of alteration rather than the duration itself. However further analysis is required to constrain the influence of other parameters that influence these spectral trends such as variations in water-rock ratios and the degree of system openness (open/close system based on local morphology).</div></div>","PeriodicalId":9847,"journal":{"name":"Chemical Geology","volume":"690 ","pages":"Article 122880"},"PeriodicalIF":3.6000,"publicationDate":"2025-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermo-temporal constraints on CM parent body via spectroscopic study of insoluble organic matter\",\"authors\":\"S. Natrajan , K.K. Marhas , V.J. Rajesh , A. Mitra\",\"doi\":\"10.1016/j.chemgeo.2025.122880\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A comprehensive study was conducted using Fourier Transform Infra-Red spectroscopy and Raman spectroscopy on chemically isolated insoluble organic matter from sixteen different carbonaceous chondrites (CI, CM) to understand the alteration duration and temperature relationships within CM- CI like bodies. The average temperatures based on disordered components of Raman spectra (T<sub>IOM</sub>), range from ~35 °C to 90 °C which are consistent with previously reported estimates. Using the established kinetic parameters based on insoluble organic matter, this study presents a novel approach to estimate duration of alteration in the CM parent body. An attempt is made to link the origin of the CM suite of samples from this study using the correlation between duration of alteration and parent body size as suggested by previous hydrothermal models. The majority of our samples fall into the category of multiple cloned small planetesimals or were part of an aggregate of these bodies (rubble pile). Infrared and Raman characteristics of Ryugu studies supports the correlation between parent body size, temperature, and the duration of alteration identified in our research. Additionally, we observe that the alteration of organic matter is regulated by the temperature of alteration rather than the duration itself. However further analysis is required to constrain the influence of other parameters that influence these spectral trends such as variations in water-rock ratios and the degree of system openness (open/close system based on local morphology).</div></div>\",\"PeriodicalId\":9847,\"journal\":{\"name\":\"Chemical Geology\",\"volume\":\"690 \",\"pages\":\"Article 122880\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-05-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Geology\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0009254125002700\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Geology","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0009254125002700","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Thermo-temporal constraints on CM parent body via spectroscopic study of insoluble organic matter
A comprehensive study was conducted using Fourier Transform Infra-Red spectroscopy and Raman spectroscopy on chemically isolated insoluble organic matter from sixteen different carbonaceous chondrites (CI, CM) to understand the alteration duration and temperature relationships within CM- CI like bodies. The average temperatures based on disordered components of Raman spectra (TIOM), range from ~35 °C to 90 °C which are consistent with previously reported estimates. Using the established kinetic parameters based on insoluble organic matter, this study presents a novel approach to estimate duration of alteration in the CM parent body. An attempt is made to link the origin of the CM suite of samples from this study using the correlation between duration of alteration and parent body size as suggested by previous hydrothermal models. The majority of our samples fall into the category of multiple cloned small planetesimals or were part of an aggregate of these bodies (rubble pile). Infrared and Raman characteristics of Ryugu studies supports the correlation between parent body size, temperature, and the duration of alteration identified in our research. Additionally, we observe that the alteration of organic matter is regulated by the temperature of alteration rather than the duration itself. However further analysis is required to constrain the influence of other parameters that influence these spectral trends such as variations in water-rock ratios and the degree of system openness (open/close system based on local morphology).
期刊介绍:
Chemical Geology is an international journal that publishes original research papers on isotopic and elemental geochemistry, geochronology and cosmochemistry.
The Journal focuses on chemical processes in igneous, metamorphic, and sedimentary petrology, low- and high-temperature aqueous solutions, biogeochemistry, the environment and cosmochemistry.
Papers that are field, experimentally, or computationally based are appropriate if they are of broad international interest. The Journal generally does not publish papers that are primarily of regional or local interest, or which are primarily focused on remediation and applied geochemistry.
The Journal also welcomes innovative papers dealing with significant analytical advances that are of wide interest in the community and extend significantly beyond the scope of what would be included in the methods section of a standard research paper.