{"title":"烯烃氢胺化和氢胺甲基化过程的多相催化研究","authors":"Hongqiao Lin, Weiping Ding, Yan Zhu","doi":"10.1002/cnma.202500038","DOIUrl":null,"url":null,"abstract":"<p>Both the intermolecular hydroamination of olefins and the hydroaminomethylation of olefins have intrigued researchers for decades and are of significance spanning fundamental research and industrial applications, due to notably atom-economic and challenging C<span></span>N bond construction. In this review, a concise summary is provided by convoluting various heterogeneous catalysis systems with supported catalysts and solid acid types. The catalytic mechanisms of the two catalytic reactions including catalyst distinguishing features, reaction pathways, and product regioselectivities are put in particular emphasis. Finally, by leaning on these fundamental insights into the heterogeneous catalysis of the hydroamination and hydroaminomethylation processes of olefins, perspectives on the design rules for highly reactive and highly selective catalysts for the two chemical processes are provided.</p>","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 5","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Insights into Heterogeneous Catalysis for the Hydroamination and Hydroaminomethylation Processes of Olefins\",\"authors\":\"Hongqiao Lin, Weiping Ding, Yan Zhu\",\"doi\":\"10.1002/cnma.202500038\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Both the intermolecular hydroamination of olefins and the hydroaminomethylation of olefins have intrigued researchers for decades and are of significance spanning fundamental research and industrial applications, due to notably atom-economic and challenging C<span></span>N bond construction. In this review, a concise summary is provided by convoluting various heterogeneous catalysis systems with supported catalysts and solid acid types. The catalytic mechanisms of the two catalytic reactions including catalyst distinguishing features, reaction pathways, and product regioselectivities are put in particular emphasis. Finally, by leaning on these fundamental insights into the heterogeneous catalysis of the hydroamination and hydroaminomethylation processes of olefins, perspectives on the design rules for highly reactive and highly selective catalysts for the two chemical processes are provided.</p>\",\"PeriodicalId\":54339,\"journal\":{\"name\":\"ChemNanoMat\",\"volume\":\"11 5\",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2025-04-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemNanoMat\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cnma.202500038\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemNanoMat","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cnma.202500038","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Insights into Heterogeneous Catalysis for the Hydroamination and Hydroaminomethylation Processes of Olefins
Both the intermolecular hydroamination of olefins and the hydroaminomethylation of olefins have intrigued researchers for decades and are of significance spanning fundamental research and industrial applications, due to notably atom-economic and challenging CN bond construction. In this review, a concise summary is provided by convoluting various heterogeneous catalysis systems with supported catalysts and solid acid types. The catalytic mechanisms of the two catalytic reactions including catalyst distinguishing features, reaction pathways, and product regioselectivities are put in particular emphasis. Finally, by leaning on these fundamental insights into the heterogeneous catalysis of the hydroamination and hydroaminomethylation processes of olefins, perspectives on the design rules for highly reactive and highly selective catalysts for the two chemical processes are provided.
ChemNanoMatEnergy-Energy Engineering and Power Technology
CiteScore
6.10
自引率
2.60%
发文量
236
期刊介绍:
ChemNanoMat is a new journal published in close cooperation with the teams of Angewandte Chemie and Advanced Materials, and is the new sister journal to Chemistry—An Asian Journal.