烯烃氢胺化和氢胺甲基化过程的多相催化研究

IF 2.6 4区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ChemNanoMat Pub Date : 2025-04-26 DOI:10.1002/cnma.202500038
Hongqiao Lin, Weiping Ding, Yan Zhu
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引用次数: 0

摘要

烯烃的分子间氢胺化和烯烃的氢胺甲基化几十年来一直引起研究人员的兴趣,并且由于原子经济和具有挑战性的C - N键构建,在基础研究和工业应用中具有重要意义。在这篇综述中,简要总结了各种具有负载催化剂和固体酸类型的多相催化体系。特别强调了两种催化反应的催化机理,包括催化剂的特征、反应途径和产物的区域选择性。最后,通过对烯烃氢胺化和氢胺甲基化过程的多相催化的这些基本见解,为这两个化学过程的高活性和高选择性催化剂的设计规则提供了观点。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Insights into Heterogeneous Catalysis for the Hydroamination and Hydroaminomethylation Processes of Olefins

Insights into Heterogeneous Catalysis for the Hydroamination and Hydroaminomethylation Processes of Olefins

Both the intermolecular hydroamination of olefins and the hydroaminomethylation of olefins have intrigued researchers for decades and are of significance spanning fundamental research and industrial applications, due to notably atom-economic and challenging CN bond construction. In this review, a concise summary is provided by convoluting various heterogeneous catalysis systems with supported catalysts and solid acid types. The catalytic mechanisms of the two catalytic reactions including catalyst distinguishing features, reaction pathways, and product regioselectivities are put in particular emphasis. Finally, by leaning on these fundamental insights into the heterogeneous catalysis of the hydroamination and hydroaminomethylation processes of olefins, perspectives on the design rules for highly reactive and highly selective catalysts for the two chemical processes are provided.

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来源期刊
ChemNanoMat
ChemNanoMat Energy-Energy Engineering and Power Technology
CiteScore
6.10
自引率
2.60%
发文量
236
期刊介绍: ChemNanoMat is a new journal published in close cooperation with the teams of Angewandte Chemie and Advanced Materials, and is the new sister journal to Chemistry—An Asian Journal.
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