稻壳源活性炭表面涂层对锂离子电池正极材料NMC 811特性及性能的影响

Fiona Angellinnov , Achmad Subhan , Wara Dyah Pita Rengga , Arif Jumari , Anne Zulfia Syahrial
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引用次数: 0

摘要

高镍含量的镍锰钴(LiNi0.8Mn0.1Co0.1O2, NMC 811)以其高容量而闻名。然而,它很容易受到空气的影响,这可能导致结构退化和容量衰退。表面涂上碳可以解决这个问题。本研究利用稻壳作为可再生的廉价碳源作为nmc811的表面涂层材料。采用氢氧化钠对稻壳进行碳化活化。采用溶液燃烧法制备了nmc811,然后采用固相法包覆稻壳,再进行煅烧。结果表明,稻壳活性炭对NMC 811的结构和形貌没有影响,但提高了其导电性和锂离子的扩散能力。在这项工作中,5 wt%稻壳衍生活性炭表面包覆NMC 811提供了44.5063 mAh/g的最高容量。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Effect of rice husk derived activated carbon surface coating on NMC 811 characteristics and performance as lithium-ion battery cathode

Effect of rice husk derived activated carbon surface coating on NMC 811 characteristics and performance as lithium-ion battery cathode
Nickel manganese cobalt with high nickel content (LiNi0.8Mn0.1Co0.1O2, NMC 811) is known for its high capacity. However, it is prone to air which could lead to structural degradation and result in capacity fading. Surface coating with carbon is known to tackle this issue. In this work, rice husk is utilized as a renewable and cheap carbon source for the surface coating material of NMC 811. Rice husk was carbonized and activated using sodium hydroxide. NMC 811 was synthesized using solution combustion and then coated with rice husk via a solid state method followed by calcination. The results showed that adding activated carbon derived from rice husk to NMC 811 did not alter its structure nor morphology, but increased conductivity and lithium-ion diffusion. In this work, 5 wt% rice husk derived activated carbon surface coated NMC 811 provided the highest capacity of 44.5063 mAh/g.
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