可回收均相Shvo催化剂†促进连续流动条件下糠醛的选择性转移加氢

IF 3.1 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Reaction Chemistry & Engineering Pub Date : 2025-05-13 DOI:10.1039/D5RE00176E

Giulia Brufani, Maitê Campos, Chiara Lenzi, Luís Adriano Santos do Nascimento, Emilia Paone, Andrea Piazzi, Rita Mazzoni, Luigi Vaccaro and Francesco Mauriello

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引用次数: 0

摘要

本文首次报道了以生物基2-甲基四氢呋喃为反应介质，2-丙醇为化学计量氢供体，均相Shvo催化剂在糠醛选择性转移加氢制糠醇中的连续流应用。均相催化剂表现出优异的可回收性，在至少五个连续的反应循环中保持高性能。该工艺代表了在连续流动条件下生物质衍生的糠醛的还原催化增值的有效和最小化浪费的策略，并得到了综合绿色指标评估的验证。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Selective transfer hydrogenation of furfural under continuous flow conditions promoted by the recoverable homogeneous Shvo's catalyst†

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Selective transfer hydrogenation of furfural under continuous flow conditions promoted by the recoverable homogeneous Shvo's catalyst†

The continuous-flow application of the homogeneous Shvo's catalyst for the selective transfer hydrogenation of furfural to furfuryl alcohol, utilizing biobased 2-methyltetrahydrofuran as the reaction medium and 2-propanol as a stoichiometric hydrogen donor is reported for the first time. The homogeneous catalyst demonstrated excellent recyclability, maintaining high performance over at least five consecutive reaction cycles. This process represents an efficient and waste-minimized strategy for the reductive catalytic valorization of biomass-derived furfural under continuous-flow conditions, as validated by a comprehensive green metrics assessment.

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来源期刊

Reaction Chemistry & Engineering Chemistry-Chemistry (miscellaneous)

CiteScore

6.60

自引率

7.70%

发文量

227

期刊介绍： Reaction Chemistry & Engineering is a new journal reporting cutting edge research into all aspects of making molecules for the benefit of fundamental research, applied processes and wider society. From fundamental, molecular-level chemistry to large scale chemical production, Reaction Chemistry & Engineering brings together communities of chemists and chemical engineers working to ensure the crucial role of reaction chemistry in today’s world.