以单晶赤铁矿为例,阐明氢基直接还原过程中的微观结构演变

IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Barak Ratzker , Martina Ruffino , Shiv Shankar , Dierk Raabe , Yan Ma
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引用次数: 0

摘要

氧化铁可持续氢基直接还原(HyDR)是降低钢铁生产碳排放的有效途径。由于微观还原行为与微观组织演变密切相关,因此了解微观还原机制具有重要意义。工业赤铁矿球团是微观结构复杂的系统,具有固有的孔隙,缺陷和杂质。因此,在本研究中,我们研究了单晶赤铁矿(700°C)的水合物,以阐明模型系统中的还原行为和微观结构演变。用热重法对单晶(SC)和工业多晶多孔球团的还原动力学进行了比较。另外制备SC样品,使其表面平行于赤铁矿的(0001)、(101¯0)、(101¯0)和(12¯10)晶体平面,然后部分还原到16%和80%的还原度。采用扫描电子显微镜和电子背散射衍射(EBSD)对其微观结构进行了全面研究。反应锋面通过收缩核模型向赤铁矿中推进,同时在磁铁矿层中形成渗透孔网络;紧随其后的是w stite和铁的形成,以及孔隙的粗化,保留的氧化物继续在整个样品中均匀地减少,遵守孔隙/颗粒模型。值得注意的是,在靠近赤铁矿/磁铁矿界面的磁铁矿中形成“细胞状”形态,“细胞内部”多孔,“细胞壁”粗糙多孔。此外,还考虑了分层孔隙形成、相变、织构和取向关系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Elucidating the microstructure evolution during hydrogen-based direct reduction via a case study of single crystal hematite

Elucidating the microstructure evolution during hydrogen-based direct reduction via a case study of single crystal hematite
Sustainable hydrogen-based direct reduction (HyDR) of iron oxide is an effective approach to reduce carbon emissions in steel production. As the reduction behaviour is closely related to the microstructure evolution, it is important to understand the microscopic reduction mechanisms. Industrial hematite pellets are microstructurally intricate systems with inherent porosity, defects, and impurities. Therefore, in the present study we investigated the HyDR of single crystal hematite (at 700 °C) to elucidate the reduction behaviour and microstructure evolution in a model system. The reduction kinetics of the single crystal (SC) were compared to those of industrial polycrystalline porous pellets using thermogravimetric analysis. Additional SC samples were prepared such that their faces are parallel to the (0001), (101¯0) and (12¯10) crystallographic planes of hematite, and then partially reduced to 16 and 80 % reduction degree. Their microstructure was thoroughly examined by scanning electron microscopy and electron backscatter diffraction (EBSD). Reaction fronts were thus shown to advance into the hematite by a shrinking core model while creating a percolating pore network in the magnetite layer; this was closely followed by wüstite and iron formation, as well as pore coarsening, with the retained oxides proceeding to reduce homogenously throughout the sample abiding by the pore/grain models. Notably, a “cell-like” morphology develops in the magnetite near the hematite/magnetite interface, with finely porous “cell interiors” surrounded by coarsely porous “cell walls”. Furthermore, the hierarchal pore formation, phase transformations, texture, and orientation relationships are considered.
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来源期刊
Acta Materialia
Acta Materialia 工程技术-材料科学:综合
CiteScore
16.10
自引率
8.50%
发文量
801
审稿时长
53 days
期刊介绍: Acta Materialia serves as a platform for publishing full-length, original papers and commissioned overviews that contribute to a profound understanding of the correlation between the processing, structure, and properties of inorganic materials. The journal seeks papers with high impact potential or those that significantly propel the field forward. The scope includes the atomic and molecular arrangements, chemical and electronic structures, and microstructure of materials, focusing on their mechanical or functional behavior across all length scales, including nanostructures.
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