{"title":"基于能量转移的Tb3+Eu3+二硅酸二钡镁荧光粉白色粉末可调发光","authors":"Dipti Shukla, Pratiksha Pandey, M. Z. Khan","doi":"10.1186/s40712-025-00280-1","DOIUrl":null,"url":null,"abstract":"<div><p>The Di barium magnesium Di-silicate Ba2MgSi2O7 (BMSO) with single-doped Tb3 + , Eu3 + phosphors, and co-doped Tb3 + /Eu3 + phosphors were prepared by the combustion method. The structural characterisation was studied by X-ray diffraction (XRD) technique, and an optical property (PL, ML) and luminescence decay curves were utilised to describe each phosphor’s properties. Profound green emission due to the Tb3 + 5D4-7F5 transition was optically canvassed in the Tb3 + single-doped Ba2MgSi2O7 sample, and it was determined that the appropriate concentration quenching process involved a diople-diople interaction. A huge overlap between Tb3 + emission and Eu3 + excitation spectra has consequences for strength transfer from Tb3 + to Eu3 + . Based on the concentration quenching approach, it was found that the energy transfer mechanism is a quadrupole–quadrupole interaction, and the energy transfer critical distance from Tb3 + to Eu3 + ions is predicted to be (6.7). Additionally, by altering the ratio of Tb3 + and Eu3 + concentrations in Ba2MgSi2O7:Tb3 + Eu3 + phosphors, white light emission was produced. According to all the findings, the single-component white light-producing phosphor BMSO: Tb3 + Eu3 + is a promising one.\n</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"20 1","pages":""},"PeriodicalIF":3.4000,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-025-00280-1","citationCount":"0","resultStr":"{\"title\":\"A novel white powder light tunable luminescence in dibarium magnesium disilicate phosphor with Tb3+Eu3+ based on energy transfer\",\"authors\":\"Dipti Shukla, Pratiksha Pandey, M. Z. Khan\",\"doi\":\"10.1186/s40712-025-00280-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Di barium magnesium Di-silicate Ba2MgSi2O7 (BMSO) with single-doped Tb3 + , Eu3 + phosphors, and co-doped Tb3 + /Eu3 + phosphors were prepared by the combustion method. The structural characterisation was studied by X-ray diffraction (XRD) technique, and an optical property (PL, ML) and luminescence decay curves were utilised to describe each phosphor’s properties. Profound green emission due to the Tb3 + 5D4-7F5 transition was optically canvassed in the Tb3 + single-doped Ba2MgSi2O7 sample, and it was determined that the appropriate concentration quenching process involved a diople-diople interaction. A huge overlap between Tb3 + emission and Eu3 + excitation spectra has consequences for strength transfer from Tb3 + to Eu3 + . Based on the concentration quenching approach, it was found that the energy transfer mechanism is a quadrupole–quadrupole interaction, and the energy transfer critical distance from Tb3 + to Eu3 + ions is predicted to be (6.7). Additionally, by altering the ratio of Tb3 + and Eu3 + concentrations in Ba2MgSi2O7:Tb3 + Eu3 + phosphors, white light emission was produced. According to all the findings, the single-component white light-producing phosphor BMSO: Tb3 + Eu3 + is a promising one.\\n</p></div>\",\"PeriodicalId\":592,\"journal\":{\"name\":\"International Journal of Mechanical and Materials Engineering\",\"volume\":\"20 1\",\"pages\":\"\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2025-05-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-025-00280-1\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Mechanical and Materials Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1186/s40712-025-00280-1\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mechanical and Materials Engineering","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1186/s40712-025-00280-1","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
A novel white powder light tunable luminescence in dibarium magnesium disilicate phosphor with Tb3+Eu3+ based on energy transfer
The Di barium magnesium Di-silicate Ba2MgSi2O7 (BMSO) with single-doped Tb3 + , Eu3 + phosphors, and co-doped Tb3 + /Eu3 + phosphors were prepared by the combustion method. The structural characterisation was studied by X-ray diffraction (XRD) technique, and an optical property (PL, ML) and luminescence decay curves were utilised to describe each phosphor’s properties. Profound green emission due to the Tb3 + 5D4-7F5 transition was optically canvassed in the Tb3 + single-doped Ba2MgSi2O7 sample, and it was determined that the appropriate concentration quenching process involved a diople-diople interaction. A huge overlap between Tb3 + emission and Eu3 + excitation spectra has consequences for strength transfer from Tb3 + to Eu3 + . Based on the concentration quenching approach, it was found that the energy transfer mechanism is a quadrupole–quadrupole interaction, and the energy transfer critical distance from Tb3 + to Eu3 + ions is predicted to be (6.7). Additionally, by altering the ratio of Tb3 + and Eu3 + concentrations in Ba2MgSi2O7:Tb3 + Eu3 + phosphors, white light emission was produced. According to all the findings, the single-component white light-producing phosphor BMSO: Tb3 + Eu3 + is a promising one.