采用离子液体模板法推进沸石设计

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
CrystEngComm Pub Date : 2025-04-10 DOI:10.1039/D5CE00253B
Tianzhao Liu, Xuemin Li, Owen J. Curnow, Jungkyu Choi and Alex C. K. Yip
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引用次数: 0

摘要

离子液体(ILs)已经成为沸石合成和结构修饰的通用工具,可以精确控制结晶、形态、孔隙度和框架设计。它们的物理化学性质,如低蒸气压、高热稳定性和可调极性,使它们能够作为溶剂、结构导向剂(sda)、多孔剂和合成后改性剂在沸石形成中发挥作用。本文重点介绍了ILs在功能化沸石合成和改性中的应用,评估了它们对沸石拓扑结构、形态和功能化沸石发展的影响,包括纳米级、层次化和应用驱动框架。通过讨论最近的进展,我们提供了对新型沸石材料的合理设计和发现的见解,促进催化,吸附和分离技术的未来创新。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Advancing zeolite design via ionic liquid templating approach

Ionic liquids (ILs) have emerged as versatile tools in zeolite synthesis and structural modification, providing precise control over crystallization, morphology, porosity, and framework design. Their physicochemical properties, such as low vapor pressure, high thermal stability, and tunable polarity, enable their role as solvents, structure-directing agents (SDAs), porogens, and post-synthetic modifiers in zeolite formation. This article highlights the use of ILs in functionalized zeolite synthesis and modification, assessing their impact on zeolite topology, morphology, and the development of functionalized zeolites, including nanosized, hierarchical, and application-driven frameworks. By discussing recent advancements, we provide insights into the rational design and discovery of novel zeolite materials, fostering future innovations in catalysis, adsorption, and separation technologies.

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来源期刊
CrystEngComm
CrystEngComm 化学-化学综合
CiteScore
5.50
自引率
9.70%
发文量
747
审稿时长
1.7 months
期刊介绍: Design and understanding of solid-state and crystalline materials
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