Srett Santitharangkun , Etienne Skrzypek , Christoph A. Hauzenberger , Raquel Gonzalez de Vega , David Clases
{"title":"利用单独居石的反应性解读多造山相(泰国Inthanon核杂岩)","authors":"Srett Santitharangkun , Etienne Skrzypek , Christoph A. Hauzenberger , Raquel Gonzalez de Vega , David Clases","doi":"10.1016/j.chemgeo.2025.122843","DOIUrl":null,"url":null,"abstract":"<div><div>Constraining the timing of tectono-thermal events in a terrane affected by several orogenic overprints is challenging. Geochronometers sensitive to magmatic as well as low- to high-grade metamorphic reactions are required. We use the reactive accessory mineral monazite in several lithologies from the Inthanon core complex (N Thailand) to decipher the evolution of this multiply deformed and metamorphosed crustal block. We define distinct domains based on the composition and zoning of monazite and infer monazite-forming reactions using textural observations. Chemical dating by EPMA is used as a reconnaissance tool to distinguish between different age populations, followed by isotopic dating by LA-ICP-MS to assess accuracy and concordance. LA-ICP-TOF-MS mapping of complexly zoned monazite grains is used to identify domains of different ages together with zones of potentially discordant U - Pb dates.</div><div>Three age populations at ca. 240–210, 80–70 and 40–20 Ma are found in monazite from paragneiss, micaschist, orthogneiss or (meta-)granite samples. Newly grown monazite domains at ∼240 and 215 Ma (Grt ± Sil gneiss) record the prograde and retrograde parts of a medium <em>P</em> <em>-</em> <em>T</em> metamorphic loop contemporary with the Indosinian orogeny. Overgrowths formed around 80 Ma are ascribed to garnet breakdown due to an amphibolite-facies overprint during Neo-Tethyan subduction. Magmatic monazite (Bt ± Ms. orthogneiss), which formed at ca. 240 Ma, partially recrystallized at 40 Ma, indicating high-grade metamorphic conditions concurrent with the India-Eurasia collision. Locally, a younger high-<em>T</em> pulse at ca. 20 Ma triggered renewed monazite growth.</div><div>Monazite tends to (re-)grow in Ca-poor bulk compositions (metasediments) but recrystallizes in Ca-richer ones (granitoids). Our study demonstrates that monazite from diverse lithologies within a core complex has the potential to record a growth/recrystallization history spanning over 200 million years, thus helping to identify individual stages of complex tectono-thermal evolutions.</div></div>","PeriodicalId":9847,"journal":{"name":"Chemical Geology","volume":"689 ","pages":"Article 122843"},"PeriodicalIF":3.6000,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Deciphering multiple orogenic phases with the reactive help of monazite (Inthanon core complex, N Thailand)\",\"authors\":\"Srett Santitharangkun , Etienne Skrzypek , Christoph A. Hauzenberger , Raquel Gonzalez de Vega , David Clases\",\"doi\":\"10.1016/j.chemgeo.2025.122843\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Constraining the timing of tectono-thermal events in a terrane affected by several orogenic overprints is challenging. Geochronometers sensitive to magmatic as well as low- to high-grade metamorphic reactions are required. We use the reactive accessory mineral monazite in several lithologies from the Inthanon core complex (N Thailand) to decipher the evolution of this multiply deformed and metamorphosed crustal block. We define distinct domains based on the composition and zoning of monazite and infer monazite-forming reactions using textural observations. Chemical dating by EPMA is used as a reconnaissance tool to distinguish between different age populations, followed by isotopic dating by LA-ICP-MS to assess accuracy and concordance. LA-ICP-TOF-MS mapping of complexly zoned monazite grains is used to identify domains of different ages together with zones of potentially discordant U - Pb dates.</div><div>Three age populations at ca. 240–210, 80–70 and 40–20 Ma are found in monazite from paragneiss, micaschist, orthogneiss or (meta-)granite samples. Newly grown monazite domains at ∼240 and 215 Ma (Grt ± Sil gneiss) record the prograde and retrograde parts of a medium <em>P</em> <em>-</em> <em>T</em> metamorphic loop contemporary with the Indosinian orogeny. Overgrowths formed around 80 Ma are ascribed to garnet breakdown due to an amphibolite-facies overprint during Neo-Tethyan subduction. Magmatic monazite (Bt ± Ms. orthogneiss), which formed at ca. 240 Ma, partially recrystallized at 40 Ma, indicating high-grade metamorphic conditions concurrent with the India-Eurasia collision. Locally, a younger high-<em>T</em> pulse at ca. 20 Ma triggered renewed monazite growth.</div><div>Monazite tends to (re-)grow in Ca-poor bulk compositions (metasediments) but recrystallizes in Ca-richer ones (granitoids). 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Deciphering multiple orogenic phases with the reactive help of monazite (Inthanon core complex, N Thailand)
Constraining the timing of tectono-thermal events in a terrane affected by several orogenic overprints is challenging. Geochronometers sensitive to magmatic as well as low- to high-grade metamorphic reactions are required. We use the reactive accessory mineral monazite in several lithologies from the Inthanon core complex (N Thailand) to decipher the evolution of this multiply deformed and metamorphosed crustal block. We define distinct domains based on the composition and zoning of monazite and infer monazite-forming reactions using textural observations. Chemical dating by EPMA is used as a reconnaissance tool to distinguish between different age populations, followed by isotopic dating by LA-ICP-MS to assess accuracy and concordance. LA-ICP-TOF-MS mapping of complexly zoned monazite grains is used to identify domains of different ages together with zones of potentially discordant U - Pb dates.
Three age populations at ca. 240–210, 80–70 and 40–20 Ma are found in monazite from paragneiss, micaschist, orthogneiss or (meta-)granite samples. Newly grown monazite domains at ∼240 and 215 Ma (Grt ± Sil gneiss) record the prograde and retrograde parts of a medium P-T metamorphic loop contemporary with the Indosinian orogeny. Overgrowths formed around 80 Ma are ascribed to garnet breakdown due to an amphibolite-facies overprint during Neo-Tethyan subduction. Magmatic monazite (Bt ± Ms. orthogneiss), which formed at ca. 240 Ma, partially recrystallized at 40 Ma, indicating high-grade metamorphic conditions concurrent with the India-Eurasia collision. Locally, a younger high-T pulse at ca. 20 Ma triggered renewed monazite growth.
Monazite tends to (re-)grow in Ca-poor bulk compositions (metasediments) but recrystallizes in Ca-richer ones (granitoids). Our study demonstrates that monazite from diverse lithologies within a core complex has the potential to record a growth/recrystallization history spanning over 200 million years, thus helping to identify individual stages of complex tectono-thermal evolutions.
期刊介绍:
Chemical Geology is an international journal that publishes original research papers on isotopic and elemental geochemistry, geochronology and cosmochemistry.
The Journal focuses on chemical processes in igneous, metamorphic, and sedimentary petrology, low- and high-temperature aqueous solutions, biogeochemistry, the environment and cosmochemistry.
Papers that are field, experimentally, or computationally based are appropriate if they are of broad international interest. The Journal generally does not publish papers that are primarily of regional or local interest, or which are primarily focused on remediation and applied geochemistry.
The Journal also welcomes innovative papers dealing with significant analytical advances that are of wide interest in the community and extend significantly beyond the scope of what would be included in the methods section of a standard research paper.