{"title":"用阳离子树脂提纯镱","authors":"Pedro A.S. Moura , Carlos A. Grande","doi":"10.1016/j.rsurfi.2025.100550","DOIUrl":null,"url":null,"abstract":"<div><div>The growing demand for high quantities of Rare Earth Elements (REE) led to the need for novel processes for their recovery and purification. Adsorption is a promising technique for purifying REE as it eliminates the use of hazardous chemicals. This work evaluates the use of the commercial polymeric resin Dowex 50W-X8 for polishing a ytterbium (Yb) stream contaminated with other REE present when recycling neo-magnets. Adsorption equilibrium isotherms and breakthrough curves of different REE (Yb, La, Nd and Er) and binary mixtures were measured. The adsorption capacity at concentrations of 300 mg L<sup>−1</sup> ranges from 179 to 205 mg g<sup>−1</sup> following the order Er > Nd > Yb > La. The steepness of the isotherms follows a different order: Nd > Er > La > Yb, indicating that Yb will be the less adsorbed REE in a mixture. A mathematical model was fitted to single component data and was successfully used to predict the behavior of binary breakthrough curves.</div></div>","PeriodicalId":21085,"journal":{"name":"Results in Surfaces and Interfaces","volume":"19 ","pages":"Article 100550"},"PeriodicalIF":0.0000,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Purification of ytterbium using a cationic resin\",\"authors\":\"Pedro A.S. Moura , Carlos A. Grande\",\"doi\":\"10.1016/j.rsurfi.2025.100550\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The growing demand for high quantities of Rare Earth Elements (REE) led to the need for novel processes for their recovery and purification. Adsorption is a promising technique for purifying REE as it eliminates the use of hazardous chemicals. This work evaluates the use of the commercial polymeric resin Dowex 50W-X8 for polishing a ytterbium (Yb) stream contaminated with other REE present when recycling neo-magnets. Adsorption equilibrium isotherms and breakthrough curves of different REE (Yb, La, Nd and Er) and binary mixtures were measured. The adsorption capacity at concentrations of 300 mg L<sup>−1</sup> ranges from 179 to 205 mg g<sup>−1</sup> following the order Er > Nd > Yb > La. The steepness of the isotherms follows a different order: Nd > Er > La > Yb, indicating that Yb will be the less adsorbed REE in a mixture. A mathematical model was fitted to single component data and was successfully used to predict the behavior of binary breakthrough curves.</div></div>\",\"PeriodicalId\":21085,\"journal\":{\"name\":\"Results in Surfaces and Interfaces\",\"volume\":\"19 \",\"pages\":\"Article 100550\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Results in Surfaces and Interfaces\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666845925001370\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Results in Surfaces and Interfaces","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666845925001370","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The growing demand for high quantities of Rare Earth Elements (REE) led to the need for novel processes for their recovery and purification. Adsorption is a promising technique for purifying REE as it eliminates the use of hazardous chemicals. This work evaluates the use of the commercial polymeric resin Dowex 50W-X8 for polishing a ytterbium (Yb) stream contaminated with other REE present when recycling neo-magnets. Adsorption equilibrium isotherms and breakthrough curves of different REE (Yb, La, Nd and Er) and binary mixtures were measured. The adsorption capacity at concentrations of 300 mg L−1 ranges from 179 to 205 mg g−1 following the order Er > Nd > Yb > La. The steepness of the isotherms follows a different order: Nd > Er > La > Yb, indicating that Yb will be the less adsorbed REE in a mixture. A mathematical model was fitted to single component data and was successfully used to predict the behavior of binary breakthrough curves.
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