(Nitrito -κ2 O, O ')双(三羟甲基氨基甲烷-液(4-fluoro-phen-yl)磷化氢-κP]银(I)。

IUCrData Pub Date : 2025-04-01 DOI:10.1107/S2414314625002962

Frederick P. Malan , Kariska Potgieter , Reinout Meijboom

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引用次数: 0

摘要

标题AgI配合物[Ag(NO2)(C18H12F3P)2]的分子结构具有围绕中心AgI原子的扭曲四面体几何结构，总键角范围为49.80(5)~ 114.92(1)°。畸变主要是由于亚硝基配体的咬角很小[49.80(5)°]。该化合物在P21/n空间群（Z = 4， Z' = 1）的不对称单元中有1个分子结晶。

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(Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I)

The significant structural feature in the title Ag^I complex is the small bite angle of the nitrito ligand [49.80 (5)°], which influences the overall geometry.

The molecular structure of the title Ag^I complex, [Ag(NO₂)(C₁₈H₁₂F₃P)₂], features a distorted tetrahedral geometry about the central Ag^I atom, with a total range of bond angles spanning from 49.80 (5) to 114.92 (1)°. The distortion arises primarily due to the small bite angle [49.80 (5)°] of the nitrito ligand. The compound crystallizes with one molecule in the asymmetric unit, in the space group P2₁/n, with Z = 4 and Z′ = 1.

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来源期刊

IUCrData

CiteScore

0.30

自引率

0.00%

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