沙拉丁(Halayeb三角)沉积物样品中持久性有机氯农药的生态毒理学研究、特征、分布和来源。

IF 3.2 3区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL
Tarek O Said, Safaa Ragab, Amany El Sikaily, Muhammad Arshad, Mohamed A Hassaan, Murat Yilmaz, Ahmed El Nemr
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引用次数: 0

摘要

这项初步研究着眼于沙拉丁地区(埃及红海沿岸)71个沉积物样本中持久性有机氯农药的浓度、来源和危害。采用常规的方法对有机氯农药残留进行研究。采用气相色谱-质谱-质谱联用技术(GC-MS/MS)测定了16种有机氯农药的残留量;选择性反应监测(SRM)技术。六氯环己烷(HCHs)、二氯二苯基三氯乙烷(DDTs)和环二烯(cd)的总农药残留(ng g-1,干重)分别从-1扩展到-1。滴滴涕的代谢物DDD和DDE在沉积物样品中含量丰富,这表明所鉴定的DDT是古老的,而不是最近添加到Shalatin地区,因为该地区附近缺乏这些代谢物的潜在来源,如河流或农业活动。沉积物样品中的有机氯农药含量低于全球其他地区的报告。对有机氯农药的来源鉴定和生态毒理学研究进行了探讨。对可能出现的健康和环境问题的分析表明,在研究区域内,对人和动物都没有太多危害。在非农业和农业用途上广泛使用有机氯农药是本研究中持久性农药的主要原因。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Eco-toxicological study, characterization, distribution and sourcing of persistent organochlorine pesticides in Shalatin (Halayeb Triangle) sediment samples.

This preliminary study looked at the concentrations, sources, and hazards of the persistent organochlorine pesticides in 71 sediment samples from the Shalatin area (Egyptian Red Sea coast). Conventional methods were used to study the persistent organochlorinated pesticide residue. The residues of 16 organochlorine pesticides were determined using the gas chromatograph-mass spectrometer-mass spectrometer (GC-MS/MS); selected reaction monitoring (SRM) technique. The total pesticide residue (ng g-1, dry weight) extended from < DL-0.628; < DL-7.128; and < DL-8.256 ng g-1 for hexachloro-cyclohexane (HCHs), dichloro-diphenyl-trichloro ethane (DDTs), and cyclodienes (CDs), respectively. DDD and DDE, metabolites of DDT, are abundant in the sediment samples, suggesting that the identified DDTs were ancient and not recently added to the Shalatin area due to the lack of potential sources of these metabolites such as rivers or agricultural activities near this area. The organochlorine pesticides in sediment samples are lower than those reported for other global regions. The source identification of organochlorine pesticides and the Eco-toxicological study were also investigated. The analysis of possible health and environmental issues showed that there were not many hazards to either people or animals in the area under study. The widespread use of organochlorine pesticides for non-agricultural and agricultural purposes is this study's leading cause of persistent pesticides.

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来源期刊
Environmental Geochemistry and Health
Environmental Geochemistry and Health 环境科学-工程:环境
CiteScore
8.00
自引率
4.80%
发文量
279
审稿时长
4.2 months
期刊介绍: Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people. Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes. The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.
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