Tarek O Said, Safaa Ragab, Amany El Sikaily, Muhammad Arshad, Mohamed A Hassaan, Murat Yilmaz, Ahmed El Nemr
{"title":"沙拉丁(Halayeb三角)沉积物样品中持久性有机氯农药的生态毒理学研究、特征、分布和来源。","authors":"Tarek O Said, Safaa Ragab, Amany El Sikaily, Muhammad Arshad, Mohamed A Hassaan, Murat Yilmaz, Ahmed El Nemr","doi":"10.1007/s10653-025-02509-6","DOIUrl":null,"url":null,"abstract":"<p><p>This preliminary study looked at the concentrations, sources, and hazards of the persistent organochlorine pesticides in 71 sediment samples from the Shalatin area (Egyptian Red Sea coast). Conventional methods were used to study the persistent organochlorinated pesticide residue. The residues of 16 organochlorine pesticides were determined using the gas chromatograph-mass spectrometer-mass spectrometer (GC-MS/MS); selected reaction monitoring (SRM) technique. The total pesticide residue (ng g<sup>-1</sup>, dry weight) extended from < DL-0.628; < DL-7.128; and < DL-8.256 ng g<sup>-1</sup> for hexachloro-cyclohexane (HCHs), dichloro-diphenyl-trichloro ethane (DDTs), and cyclodienes (CDs), respectively. DDD and DDE, metabolites of DDT, are abundant in the sediment samples, suggesting that the identified DDTs were ancient and not recently added to the Shalatin area due to the lack of potential sources of these metabolites such as rivers or agricultural activities near this area. The organochlorine pesticides in sediment samples are lower than those reported for other global regions. The source identification of organochlorine pesticides and the Eco-toxicological study were also investigated. The analysis of possible health and environmental issues showed that there were not many hazards to either people or animals in the area under study. The widespread use of organochlorine pesticides for non-agricultural and agricultural purposes is this study's leading cause of persistent pesticides.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 6","pages":"205"},"PeriodicalIF":3.2000,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Eco-toxicological study, characterization, distribution and sourcing of persistent organochlorine pesticides in Shalatin (Halayeb Triangle) sediment samples.\",\"authors\":\"Tarek O Said, Safaa Ragab, Amany El Sikaily, Muhammad Arshad, Mohamed A Hassaan, Murat Yilmaz, Ahmed El Nemr\",\"doi\":\"10.1007/s10653-025-02509-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>This preliminary study looked at the concentrations, sources, and hazards of the persistent organochlorine pesticides in 71 sediment samples from the Shalatin area (Egyptian Red Sea coast). Conventional methods were used to study the persistent organochlorinated pesticide residue. The residues of 16 organochlorine pesticides were determined using the gas chromatograph-mass spectrometer-mass spectrometer (GC-MS/MS); selected reaction monitoring (SRM) technique. The total pesticide residue (ng g<sup>-1</sup>, dry weight) extended from < DL-0.628; < DL-7.128; and < DL-8.256 ng g<sup>-1</sup> for hexachloro-cyclohexane (HCHs), dichloro-diphenyl-trichloro ethane (DDTs), and cyclodienes (CDs), respectively. DDD and DDE, metabolites of DDT, are abundant in the sediment samples, suggesting that the identified DDTs were ancient and not recently added to the Shalatin area due to the lack of potential sources of these metabolites such as rivers or agricultural activities near this area. The organochlorine pesticides in sediment samples are lower than those reported for other global regions. The source identification of organochlorine pesticides and the Eco-toxicological study were also investigated. The analysis of possible health and environmental issues showed that there were not many hazards to either people or animals in the area under study. 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Eco-toxicological study, characterization, distribution and sourcing of persistent organochlorine pesticides in Shalatin (Halayeb Triangle) sediment samples.
This preliminary study looked at the concentrations, sources, and hazards of the persistent organochlorine pesticides in 71 sediment samples from the Shalatin area (Egyptian Red Sea coast). Conventional methods were used to study the persistent organochlorinated pesticide residue. The residues of 16 organochlorine pesticides were determined using the gas chromatograph-mass spectrometer-mass spectrometer (GC-MS/MS); selected reaction monitoring (SRM) technique. The total pesticide residue (ng g-1, dry weight) extended from < DL-0.628; < DL-7.128; and < DL-8.256 ng g-1 for hexachloro-cyclohexane (HCHs), dichloro-diphenyl-trichloro ethane (DDTs), and cyclodienes (CDs), respectively. DDD and DDE, metabolites of DDT, are abundant in the sediment samples, suggesting that the identified DDTs were ancient and not recently added to the Shalatin area due to the lack of potential sources of these metabolites such as rivers or agricultural activities near this area. The organochlorine pesticides in sediment samples are lower than those reported for other global regions. The source identification of organochlorine pesticides and the Eco-toxicological study were also investigated. The analysis of possible health and environmental issues showed that there were not many hazards to either people or animals in the area under study. The widespread use of organochlorine pesticides for non-agricultural and agricultural purposes is this study's leading cause of persistent pesticides.
期刊介绍:
Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people.
Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes.
The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.