n -亚甲酰胺的生成与紫外光解

IF 7.6 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chemical Science Pub Date : 2025-05-15 DOI:10.1039/d5sc02777b

Viktor Paczelt, Vladimir Drabkin, Daniel Kühn, André K. Eckhardt

引用次数: 0

摘要

简单亚胺，包括n -亚甲酰胺，是较大的生物化合物的关键。本研究通过高真空闪蒸热解重温了其形成过程，并利用低温基质分离红外和紫外/可见光谱对其进行了表征。它的稳定性、分解产物以及与星际和益生元化学的相关性得到了实验和计算分析的支持。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Generation and UV-photolysis of N-methyleneformamide

Simple imines, including N-methyleneformamide, are key to larger biological compounds. This study revisits its formation via high-vacuum flash pyrolysis and characterizes it using cryogenic matrix isolation IR and UV/Vis spectroscopy. Its stability, decomposition products, and relevance to interstellar and prebiotic chemistry are supported by experiments and computational analysis.

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来源期刊

Chemical Science CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

14.40

自引率

4.80%

发文量

1352

审稿时长

2.1 months

期刊介绍： Chemical Science is a journal that encompasses various disciplines within the chemical sciences. Its scope includes publishing ground-breaking research with significant implications for its respective field, as well as appealing to a wider audience in related areas. To be considered for publication, articles must showcase innovative and original advances in their field of study and be presented in a manner that is understandable to scientists from diverse backgrounds. However, the journal generally does not publish highly specialized research.