Márcio Fernando dos Santos Albuquerque , Adriana Maria Coimbra Horbe , Cécile Gautheron , João Gabriel Cavalcante Vieira , Pedro Val , Rosella Pinna-Jamme , Carlos Alejandro Salazar
{"title":"中-北亚马逊地区铁和铁红土硬壳和铝土矿的(u)/He年代学:对古气候和景观演化的启示","authors":"Márcio Fernando dos Santos Albuquerque , Adriana Maria Coimbra Horbe , Cécile Gautheron , João Gabriel Cavalcante Vieira , Pedro Val , Rosella Pinna-Jamme , Carlos Alejandro Salazar","doi":"10.1016/j.chemgeo.2025.122835","DOIUrl":null,"url":null,"abstract":"<div><div>Over the past 100 million years, intense lateritization has resulted in the widespread development of Fe, Fe<img>Al, and bauxite lateritic duricrusts across Amazonia. In Central-Northern Amazonia, Fe-rich lateritic duricrusts formed around 44 Ma, with peaks at 11–10 Ma and 5–4 Ma, while bauxite formation occurred between 25 and 15 Ma. Expanding this interpretation to the Amazonian region, two main bauxitization episodes have been identified: (i) between 30 and 15 Ma and (ii) post-15 Ma, most pronounced at ∼3–4 Ma. These lateritic duricrusts suggest that lateritization persisted from the Eocene to the Pliocene. This indicates a predominantly humid, well-drained climate conducive to goethite (bauxite) formation, overprinted by drier ferruginization pulses associated with global climatic fluctuations.</div><div>These lateritic duricrusts have acted as effective erosion-resistant surfaces, forming three distinct geomorphic levels. Surface 1 (S1, >240 m a.s.l.) and Surface 2 (S2, 100–240 m a.s.l.), characterized by extensive bauxite and Fe<img>Al lateritic duricrusts, developed at ∼20 Ma and between ∼17 and ∼ 11–5 Ma, respectively. Surface 3 (S3, <100 m a.s.l.) formed under intense ferruginous lateritization at ∼4 Ma. A progressive decrease in goethite ages and Al content from S1 to S3 reflects increasing landscape dissection. Furthermore, (U<img>Th)/He data reveal a significant fluvial incision rate of 28 m/Ma, suggesting pronounced landscape rejuvenation, particularly between 10 and 3 Ma, which overprints older weathering phases preserved in southern Amazonia. Neotectonic activity facilitated the preservation of complete lateritic profiles on hilltops and plateaus, whereas truncated profiles with stone lines characterize valley slopes.</div></div>","PeriodicalId":9847,"journal":{"name":"Chemical Geology","volume":"689 ","pages":"Article 122835"},"PeriodicalIF":3.6000,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"(UTh)/He Geochronology of Fe and FeAl Lateritic Duricrusts and Bauxites in Central-Northern Amazonia: Implications for Paleoclimate and Landscape Evolution\",\"authors\":\"Márcio Fernando dos Santos Albuquerque , Adriana Maria Coimbra Horbe , Cécile Gautheron , João Gabriel Cavalcante Vieira , Pedro Val , Rosella Pinna-Jamme , Carlos Alejandro Salazar\",\"doi\":\"10.1016/j.chemgeo.2025.122835\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Over the past 100 million years, intense lateritization has resulted in the widespread development of Fe, Fe<img>Al, and bauxite lateritic duricrusts across Amazonia. In Central-Northern Amazonia, Fe-rich lateritic duricrusts formed around 44 Ma, with peaks at 11–10 Ma and 5–4 Ma, while bauxite formation occurred between 25 and 15 Ma. Expanding this interpretation to the Amazonian region, two main bauxitization episodes have been identified: (i) between 30 and 15 Ma and (ii) post-15 Ma, most pronounced at ∼3–4 Ma. These lateritic duricrusts suggest that lateritization persisted from the Eocene to the Pliocene. This indicates a predominantly humid, well-drained climate conducive to goethite (bauxite) formation, overprinted by drier ferruginization pulses associated with global climatic fluctuations.</div><div>These lateritic duricrusts have acted as effective erosion-resistant surfaces, forming three distinct geomorphic levels. Surface 1 (S1, >240 m a.s.l.) and Surface 2 (S2, 100–240 m a.s.l.), characterized by extensive bauxite and Fe<img>Al lateritic duricrusts, developed at ∼20 Ma and between ∼17 and ∼ 11–5 Ma, respectively. Surface 3 (S3, <100 m a.s.l.) formed under intense ferruginous lateritization at ∼4 Ma. A progressive decrease in goethite ages and Al content from S1 to S3 reflects increasing landscape dissection. Furthermore, (U<img>Th)/He data reveal a significant fluvial incision rate of 28 m/Ma, suggesting pronounced landscape rejuvenation, particularly between 10 and 3 Ma, which overprints older weathering phases preserved in southern Amazonia. Neotectonic activity facilitated the preservation of complete lateritic profiles on hilltops and plateaus, whereas truncated profiles with stone lines characterize valley slopes.</div></div>\",\"PeriodicalId\":9847,\"journal\":{\"name\":\"Chemical Geology\",\"volume\":\"689 \",\"pages\":\"Article 122835\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Geology\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0009254125002256\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Geology","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0009254125002256","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
(UTh)/He Geochronology of Fe and FeAl Lateritic Duricrusts and Bauxites in Central-Northern Amazonia: Implications for Paleoclimate and Landscape Evolution
Over the past 100 million years, intense lateritization has resulted in the widespread development of Fe, FeAl, and bauxite lateritic duricrusts across Amazonia. In Central-Northern Amazonia, Fe-rich lateritic duricrusts formed around 44 Ma, with peaks at 11–10 Ma and 5–4 Ma, while bauxite formation occurred between 25 and 15 Ma. Expanding this interpretation to the Amazonian region, two main bauxitization episodes have been identified: (i) between 30 and 15 Ma and (ii) post-15 Ma, most pronounced at ∼3–4 Ma. These lateritic duricrusts suggest that lateritization persisted from the Eocene to the Pliocene. This indicates a predominantly humid, well-drained climate conducive to goethite (bauxite) formation, overprinted by drier ferruginization pulses associated with global climatic fluctuations.
These lateritic duricrusts have acted as effective erosion-resistant surfaces, forming three distinct geomorphic levels. Surface 1 (S1, >240 m a.s.l.) and Surface 2 (S2, 100–240 m a.s.l.), characterized by extensive bauxite and FeAl lateritic duricrusts, developed at ∼20 Ma and between ∼17 and ∼ 11–5 Ma, respectively. Surface 3 (S3, <100 m a.s.l.) formed under intense ferruginous lateritization at ∼4 Ma. A progressive decrease in goethite ages and Al content from S1 to S3 reflects increasing landscape dissection. Furthermore, (UTh)/He data reveal a significant fluvial incision rate of 28 m/Ma, suggesting pronounced landscape rejuvenation, particularly between 10 and 3 Ma, which overprints older weathering phases preserved in southern Amazonia. Neotectonic activity facilitated the preservation of complete lateritic profiles on hilltops and plateaus, whereas truncated profiles with stone lines characterize valley slopes.
期刊介绍:
Chemical Geology is an international journal that publishes original research papers on isotopic and elemental geochemistry, geochronology and cosmochemistry.
The Journal focuses on chemical processes in igneous, metamorphic, and sedimentary petrology, low- and high-temperature aqueous solutions, biogeochemistry, the environment and cosmochemistry.
Papers that are field, experimentally, or computationally based are appropriate if they are of broad international interest. The Journal generally does not publish papers that are primarily of regional or local interest, or which are primarily focused on remediation and applied geochemistry.
The Journal also welcomes innovative papers dealing with significant analytical advances that are of wide interest in the community and extend significantly beyond the scope of what would be included in the methods section of a standard research paper.