Luka Vinko*, Iztok Devetak and Mojca Bavcon Kralj,
{"title":"揭示未来水生环境挑战:职前化学教师对微塑料吸附内分泌干扰物的研究","authors":"Luka Vinko*, Iztok Devetak and Mojca Bavcon Kralj, ","doi":"10.1021/acs.jchemed.5c0002510.1021/acs.jchemed.5c00025","DOIUrl":null,"url":null,"abstract":"<p >Water resources are subject to an increasing number of different types of pollutants, chemical and physical, which can interact in different ways. Among these, microplastic particles (MPs) and pharmaceuticals often coexist, with MPs serving as potential carriers for them. This interaction poses dual risks, including physical harm and chemical intoxication upon ingestion, since MPs prolong their presence in aquatic ecosystems and organisms. Besides, both microplastics (MPs) and pharmaceuticals cannot be completely removed by current wastewater treatment technologies and are prone to cycle in the hydrosphere. To address these concerns, an inquiry-based laboratory module was implemented in a Fundamentals of Environmental Chemistry course to engage preservice chemistry teachers in investigating the adsorption of pharmaceuticals onto MPs. A total of 21 students, working in groups of 2–3, participated in two iterations of the 3 h module, which aimed to address water pollution challenges. Students identified research questions, formulated hypotheses, and designed experimental plans to assess the adsorption of drospirenone and diclofenac on four MP types: polyethylene (PE), polystyrene (PS), polyethylene terephthalate (PET), and poly(butylene adipate) terephthalate (PBAT). The pharmaceuticals’ concentrations were analyzed pre- and postexperiment using UV–vis spectrophotometry. Results indicated a higher adsorption of diclofenac compared with drospirenone, with PBAT showing superior adsorption capacity for both pharmaceuticals. One-way ANOVA identified significant differences in adsorption among MPs, particularly between PBAT and other types of MPs. Students’ environmental competencies improved after the activity, as suggested by pre- and postquestionnaire comparisons.</p>","PeriodicalId":43,"journal":{"name":"Journal of Chemical Education","volume":"102 5","pages":"2112–2119 2112–2119"},"PeriodicalIF":2.5000,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.jchemed.5c00025","citationCount":"0","resultStr":"{\"title\":\"Revealing Future Aquatic Environmental Challenges: Preservice Chemistry Teachers’ Study on Adsorption of Endocrine Disruptors on Microplastics\",\"authors\":\"Luka Vinko*, Iztok Devetak and Mojca Bavcon Kralj, \",\"doi\":\"10.1021/acs.jchemed.5c0002510.1021/acs.jchemed.5c00025\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Water resources are subject to an increasing number of different types of pollutants, chemical and physical, which can interact in different ways. Among these, microplastic particles (MPs) and pharmaceuticals often coexist, with MPs serving as potential carriers for them. This interaction poses dual risks, including physical harm and chemical intoxication upon ingestion, since MPs prolong their presence in aquatic ecosystems and organisms. Besides, both microplastics (MPs) and pharmaceuticals cannot be completely removed by current wastewater treatment technologies and are prone to cycle in the hydrosphere. To address these concerns, an inquiry-based laboratory module was implemented in a Fundamentals of Environmental Chemistry course to engage preservice chemistry teachers in investigating the adsorption of pharmaceuticals onto MPs. A total of 21 students, working in groups of 2–3, participated in two iterations of the 3 h module, which aimed to address water pollution challenges. Students identified research questions, formulated hypotheses, and designed experimental plans to assess the adsorption of drospirenone and diclofenac on four MP types: polyethylene (PE), polystyrene (PS), polyethylene terephthalate (PET), and poly(butylene adipate) terephthalate (PBAT). The pharmaceuticals’ concentrations were analyzed pre- and postexperiment using UV–vis spectrophotometry. Results indicated a higher adsorption of diclofenac compared with drospirenone, with PBAT showing superior adsorption capacity for both pharmaceuticals. One-way ANOVA identified significant differences in adsorption among MPs, particularly between PBAT and other types of MPs. Students’ environmental competencies improved after the activity, as suggested by pre- and postquestionnaire comparisons.</p>\",\"PeriodicalId\":43,\"journal\":{\"name\":\"Journal of Chemical Education\",\"volume\":\"102 5\",\"pages\":\"2112–2119 2112–2119\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2025-04-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.acs.org/doi/epdf/10.1021/acs.jchemed.5c00025\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Education\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.jchemed.5c00025\",\"RegionNum\":3,\"RegionCategory\":\"教育学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Education","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.jchemed.5c00025","RegionNum":3,"RegionCategory":"教育学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Revealing Future Aquatic Environmental Challenges: Preservice Chemistry Teachers’ Study on Adsorption of Endocrine Disruptors on Microplastics
Water resources are subject to an increasing number of different types of pollutants, chemical and physical, which can interact in different ways. Among these, microplastic particles (MPs) and pharmaceuticals often coexist, with MPs serving as potential carriers for them. This interaction poses dual risks, including physical harm and chemical intoxication upon ingestion, since MPs prolong their presence in aquatic ecosystems and organisms. Besides, both microplastics (MPs) and pharmaceuticals cannot be completely removed by current wastewater treatment technologies and are prone to cycle in the hydrosphere. To address these concerns, an inquiry-based laboratory module was implemented in a Fundamentals of Environmental Chemistry course to engage preservice chemistry teachers in investigating the adsorption of pharmaceuticals onto MPs. A total of 21 students, working in groups of 2–3, participated in two iterations of the 3 h module, which aimed to address water pollution challenges. Students identified research questions, formulated hypotheses, and designed experimental plans to assess the adsorption of drospirenone and diclofenac on four MP types: polyethylene (PE), polystyrene (PS), polyethylene terephthalate (PET), and poly(butylene adipate) terephthalate (PBAT). The pharmaceuticals’ concentrations were analyzed pre- and postexperiment using UV–vis spectrophotometry. Results indicated a higher adsorption of diclofenac compared with drospirenone, with PBAT showing superior adsorption capacity for both pharmaceuticals. One-way ANOVA identified significant differences in adsorption among MPs, particularly between PBAT and other types of MPs. Students’ environmental competencies improved after the activity, as suggested by pre- and postquestionnaire comparisons.
期刊介绍:
The Journal of Chemical Education is the official journal of the Division of Chemical Education of the American Chemical Society, co-published with the American Chemical Society Publications Division. Launched in 1924, the Journal of Chemical Education is the world’s premier chemical education journal. The Journal publishes peer-reviewed articles and related information as a resource to those in the field of chemical education and to those institutions that serve them. JCE typically addresses chemical content, activities, laboratory experiments, instructional methods, and pedagogies. The Journal serves as a means of communication among people across the world who are interested in the teaching and learning of chemistry. This includes instructors of chemistry from middle school through graduate school, professional staff who support these teaching activities, as well as some scientists in commerce, industry, and government.