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镧系催化剂催化合成大环四氧二硫代螺烷

IF 0.8 4区 化学 Q4 CHEMISTRY, ORGANIC
Russian Journal of Organic Chemistry Pub Date : 2025-05-07 DOI:10.1134/S1070428024603765
N. N. Makhmudiyarova, I. R. Ishmukhametova, U. M. Dzhemilev
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引用次数: 0

摘要

研究了在镧系催化剂的作用下，烷烃-α，ω-二硫醇（丁烷-1,4-二硫醇、戊烷-1,5-二硫醇和己烷-1,6-二硫醇）与1,1-二氢过氧环烷烃和甲醛进行环缩合反应合成大环四氧二硫醇的有效方法。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
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Synthesis of Macrocyclic Tetraoxadithiaspiroalkanes in the Presence of Lanthanide Catalysts

An efficient method has been developed for the synthesis of macrocyclic tetraoxadithiaspiroalkanes by the cyclocondensation of alkane-α,ω-dithiols (butane-1,4-dithiol, pentane-1,5-dithiol, and hexane-1,6-dithiol) with 1,1-dihydroperoxycycloalkanes and formaldehyde in the presence of lanthanide catalysts.

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来源期刊
Russian Journal of Organic Chemistry
Russian Journal of Organic Chemistry 化学-有机化学
CiteScore
1.40
自引率
25.00%
发文量
139
审稿时长
3-6 weeks
期刊介绍： Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.
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