基于2-单苯肼苊-1- 1的钯（II）配位化合物的合成、结构与性能

IF 1.2 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2025-05-07 DOI:10.1134/S002247662504016X

A. K. Gukova, V. I. Komlyagina, I. V. Bakaev, E. V. Chekhov, I. S. Fomenko, N. F. Romashev, A. L. Gushchin

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引用次数: 0

摘要

在三酸银存在下，[Pd(phen)Cl2]与2-单苯肼苊-1- 1 （Ph-mhan）相互作用制备了[Pd(phen)(Ph-mhan)]（OTf）配位化合物。在反应过程中，Ph-mhan被去质子化，并作为阴离子与Pd（II）离子配位。所得化合物经元素分析、IR和1H NMR表征；用XRD测定了其晶体结构；分别用循环伏安法和电子吸收光谱法研究了其电化学和光学性质。

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Palladium(II) Coordination Compound Based on 2-Monophenylhydrazinoacenaphthene-1-One: Synthesis, Structure, and Properties

The [Pd(phen)(Ph-mhan)](OTf) coordination compound is prepared by the interaction of [Pd(phen)Cl₂] with 2-monophenylhydrazinoacenaphthene-1-one (Ph-mhan) in the presence of silver triflate. During the reaction, Ph-mhan is deprotonated and is coordinated to the Pd(II) ion as an anion. The obtained compound is characterized by elemental analysis, IR, and ¹H NMR spectroscopy; its crystal structure is determined by XRD; electrochemical and optical properties are studied by cyclic voltammetry and electron absorption spectroscopy, respectively.

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来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.