1,2-萘醌分子水合物中氢配合物的结构

IF 0.48 Q4 Physics and Astronomy

Bulletin of the Russian Academy of Sciences: Physics Pub Date : 2025-05-05 DOI:10.1134/S1062873824710286

S. N. Tseplina, E. E. Tseplin

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引用次数: 0

摘要

考虑了1,2-萘醌分子水合壳与水分子形成的氢配合物的定量组成和结构问题。通过将n = 5-13个水分子的氢配合物形成过程中电子跃迁的计算位移与1,2-萘醌在水溶液和正己烷溶液中的吸收带的实验位移进行比较，解决了这个问题。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Structure of Hydrogen Complexes in Hydrates of the 1,2-Naphthoquinone Molecule

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Structure of Hydrogen Complexes in Hydrates of the 1,2-Naphthoquinone Molecule

The question of the quantitative composition and structure of the formed hydrogen complexes of the 1,2-naphthoquinone molecule with water molecules in its hydration shell is considered. The problem was solved by comparing the calculated shifts of electronic transitions during the formation of hydrogen complexes with n = 5–13 water molecules with the experimental shifts of the absorption bands of 1,2-naphthoquinone in a water solution compared to a solution in n-hexane.

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来源期刊

Bulletin of the Russian Academy of Sciences: Physics Physics and Astronomy-Physics and Astronomy (all)

CiteScore

0.90

自引率

0.00%

发文量

251

期刊介绍： Bulletin of the Russian Academy of Sciences: Physics is an international peer reviewed journal published with the participation of the Russian Academy of Sciences. It presents full-text articles (regular, letters to the editor, reviews) with the most recent results in miscellaneous fields of physics and astronomy: nuclear physics, cosmic rays, condensed matter physics, plasma physics, optics and photonics, nanotechnologies, solar and astrophysics, physical applications in material sciences, life sciences, etc. Bulletin of the Russian Academy of Sciences: Physics focuses on the most relevant multidisciplinary topics in natural sciences, both fundamental and applied. Manuscripts can be submitted in Russian and English languages and are subject to peer review. Accepted articles are usually combined in thematic issues on certain topics according to the journal editorial policy. Authors featured in the journal represent renowned scientific laboratories and institutes from different countries, including large international collaborations. There are globally recognized researchers among the authors: Nobel laureates and recipients of other awards, and members of national academies of sciences and international scientific societies.