Feng-Wen Zhang, Yu-Lan Xie, Pei-Guo Liu, Meng-Qiang Li, Yi-Xuan Yang, Hao-Fei Ni, Gele Teri, Ming Zhu, Chang-Feng Wang, Yi Zhang and Da-Wei Fu
{"title":"具有可切换介电行为的三维无金属钙钛矿†","authors":"Feng-Wen Zhang, Yu-Lan Xie, Pei-Guo Liu, Meng-Qiang Li, Yi-Xuan Yang, Hao-Fei Ni, Gele Teri, Ming Zhu, Chang-Feng Wang, Yi Zhang and Da-Wei Fu","doi":"10.1039/D5CE00294J","DOIUrl":null,"url":null,"abstract":"<p >We reported a novel three-dimensional metal-free perovskite, MPZ–NH<small><sub>4</sub></small>–(BF<small><sub>4</sub></small>)<small><sub>3</sub></small> (MPZ = methylpiperazine), which exhibits a reversible phase transition accompanied by high and low dielectric state switching behavior at 382 K. This work expands the family of switchable dielectric materials and provides new insights into the design of perovskite dielectric switching materials.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 18","pages":" 2810-2814"},"PeriodicalIF":2.6000,"publicationDate":"2025-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Three-dimensional metal-free perovskite with switchable dielectric behaviors†\",\"authors\":\"Feng-Wen Zhang, Yu-Lan Xie, Pei-Guo Liu, Meng-Qiang Li, Yi-Xuan Yang, Hao-Fei Ni, Gele Teri, Ming Zhu, Chang-Feng Wang, Yi Zhang and Da-Wei Fu\",\"doi\":\"10.1039/D5CE00294J\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >We reported a novel three-dimensional metal-free perovskite, MPZ–NH<small><sub>4</sub></small>–(BF<small><sub>4</sub></small>)<small><sub>3</sub></small> (MPZ = methylpiperazine), which exhibits a reversible phase transition accompanied by high and low dielectric state switching behavior at 382 K. This work expands the family of switchable dielectric materials and provides new insights into the design of perovskite dielectric switching materials.</p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 18\",\"pages\":\" 2810-2814\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2025-04-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d5ce00294j\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d5ce00294j","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Three-dimensional metal-free perovskite with switchable dielectric behaviors†
We reported a novel three-dimensional metal-free perovskite, MPZ–NH4–(BF4)3 (MPZ = methylpiperazine), which exhibits a reversible phase transition accompanied by high and low dielectric state switching behavior at 382 K. This work expands the family of switchable dielectric materials and provides new insights into the design of perovskite dielectric switching materials.