芳基三氮烯与CO2的电化学脱胺羧基化制备芳基羧酸

IF 5 1区 化学 Q1 CHEMISTRY, ORGANIC
Lan Zhao, An-Guo Wu, Hong-Ru Li, Alexander O. Terent’ev and Liang-Nian He*, 
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引用次数: 0

摘要

利用二氧化碳作为一种有吸引力的化学原料,生产各种有合成价值的产品,这一技术正在不断发展,有可能减轻对石油化学的依赖。本文报道了用CO2催化芳基三嗪的电化学脱胺羧化反应的第一个例子。该反应可以在温和和无催化剂的条件下进行,使用可持续的方法,以二氧化碳作为绿色C1构建块,有效地将各种容易获得的芳基三嗪转化为合成有价值的羧酸。特别是,通过脱胺羧基化形成的C-C键将是合成工具箱中一个有影响的补充。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Electrochemical Deaminative Carboxylation of Aryltriazenes with CO2 to Aryl Carboxylic Acids

Electrochemical Deaminative Carboxylation of Aryltriazenes with CO2 to Aryl Carboxylic Acids

The utilization of CO2 as an appealing chemical feedstock for diverse synthetically valuable products is constantly evolving, potentially alleviating chemical production that relies on petrochemistry. Herein we report the first example of the electrochemical deaminative carboxylation of aryltriazenes with CO2. The reaction can be performed under mild and catalyst-free conditions by using sustainable methods with CO2 as a green C1 building block, efficiently converting a diverse range of readily available aryltriazenes into synthetically valuable carboxylic acids. In particular, the formation of C–C bonds by deaminative carboxylation would be an impactful addition to the synthesis toolbox.

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来源期刊
Organic Letters
Organic Letters 化学-有机化学
CiteScore
9.30
自引率
11.50%
发文量
1607
审稿时长
1.5 months
期刊介绍: Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.
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