Aderemi Babatunde Alabi, Marco Villani, Valentina Sinisi, Stefano Rampino, Nicola Coppede, Samuel Adebayo, Haleemat Iyabode Adegoke, Samson Ibukun Akinsola
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引用次数: 0
摘要
纺织工业的有毒染料造成的废水污染是一个全球性的挑战,威胁着农业生产力、粮食安全以及牲畜获得清洁水的机会。近年来,利用半导体材料光催化降解有机污染物已成为一种有前景的可持续废水处理方法。我们提出了一种具有成本效益的合成锂锰氧化物(Li2MnO3)的方法,其聚集形成致密的微晶粉末,具有光滑的石头形态和单斜晶结构。光学特性表明,该材料具有较宽的可见光吸收、较强的红外反射率和2.1 eV的光学带隙,在抗辐射涂层中具有潜在的应用前景。此外,所得的Li2MnO3材料在625 nm的光照下,在60分钟内有效地降解了常见的纺织染料Eriochrome Black T,在5 × 10⁻5 M溶液中,效率高达73%。这些发现强调了Li2MnO3纳米结构微晶体在废水处理应用中的潜力。
Lithium Manganese Oxide (Li2MnO3) as a promising photocatalyst for the degradation of Eriochrome Black T
Wastewater pollution caused by toxic dyes from the textile industry is a global challenge, threatening agricultural productivity, food security, and access to clean water for livestock. In recent years, photocatalytic degradation of organic pollutants using semiconducting materials has emerged as a promising approach for sustainable wastewater treatment. We present a cost-effective synthesis method for lithium manganese oxide (Li2MnO3), which aggregate to form a densely packed microcrystalline powder, with smooth-stone morphology, and monoclinic crystal structure. Optical characterization reveals broad visible light absorption, strong infrared reflectance and an optical bandgap of 2.1 eV, suggesting potential applications in radiation-resistant coatings. Moreover, the obtained Li2MnO3 material effectively degraded Eriochrome Black T, a common textile dye, with efficiencies up to 73% for 5 × 10⁻5 M solutions, under illumination at 625 nm, within 60 min. These findings underscore the potential of Li2MnO3 nanostructured microcrystals for wastewater treatment applications.