金/铜双催化苯乙烯与亚磷酸盐环化：二苯并膦孔的合成策略

IF 4.9 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-04-27 DOI:10.1021/acs.orglett.5c01178

Donghwa Shin, Seo-Jung Han

引用次数: 0

摘要

通过金和铜催化芳烃和亚磷酸盐的环化反应，研究了二苯并膦孔的合成方法。该反应条件具有广泛的官能团耐受性，可合成多种二苯并膦孔5-氧化物。该方法可用于制备具有独特光学和电子性质的二苯并膦孔。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Gold/Copper Dual-Catalyzed Annulation of Arynes with Phosphites: A Synthetic Strategy for Dibenzophospholes

查看原文本刊更多论文

Gold/Copper Dual-Catalyzed Annulation of Arynes with Phosphites: A Synthetic Strategy for Dibenzophospholes

A synthetic approach to dibenzophospholes was developed via the gold- and copper-catalyzed annulation reactions of arynes and phosphites. The reaction conditions demonstrated a broad functional group tolerance, enabling the synthesis of a diverse range of dibenzophosphole 5-oxides. This method is useful for preparing dibenzophospholes with unique optical and electronic properties.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.