可见光下g-C3N4/NaI双催化烯烃与杂芳烃和氨基甲酸甲酯的双官能化

IF 4.9 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-04-26 DOI:10.1021/acs.orglett.5c01200

Kai Zheng, Chao Chen, Yacong Wang, Hao Xu, Kai Ge, Chao Shen

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引用次数: 0

摘要

本文建立了一个由g-C3N4和NaI组成的光诱导非均相催化体系，用于烯烃与杂环芳烃和氨基甲酸甲酯的双官能化反应。这种方法以其广泛的底物耐受性而闻名，包括广泛的烯烃和杂芳烃，并导致形成相应的酯，产率中等至良好。此外，合成过程的可扩展性和产品转化的多功能性已经说明，突出其在有机合成中的实际应用潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Heterogeneous g-C3N4/NaI Dual Catalytic Difunctionalization of Alkenes with Heteroarenes and Methyl Carbazate under Visible Light

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Heterogeneous g-C3N4/NaI Dual Catalytic Difunctionalization of Alkenes with Heteroarenes and Methyl Carbazate under Visible Light

Herein, a photoinduced heterogeneous catalytic system merging g-C₃N₄ and NaI has been established for the difunctionalization of alkenes in conjunction with heteroarenes and methyl carbazate. This approach is notable for its broad substrate tolerance, encompassing a wide range of alkenes and heteroarenes and leading to the formation of the corresponding esters with moderate to good yields. Additionally, the scalability of the synthetic process and the versatility of the product transformations have been illustrated, highlighting its potential for practical application in organic synthesis.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.