紫外光驱动光催化剂负载Pt纳米粒子的ZnO微花的合成与表征

IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL
Anukorn Phuruangrat, Yothin Chimupala, Asanee Somdee, Titipun Thongtem, Somchai Thongtem
{"title":"紫外光驱动光催化剂负载Pt纳米粒子的ZnO微花的合成与表征","authors":"Anukorn Phuruangrat,&nbsp;Yothin Chimupala,&nbsp;Asanee Somdee,&nbsp;Titipun Thongtem,&nbsp;Somchai Thongtem","doi":"10.1134/S0036024425700414","DOIUrl":null,"url":null,"abstract":"<p>ZnO micro-flowers with and without the loaded 0.5–3.0% Pt nanoparticles as UV-light-driven photocatalyst were successfully prepared by microwave assisted-deposition method. The as-synthesized samples were composed of pure phase of wurtzite hexagonal ZnO micro-flowers the diameter of 3–5 μm and uniform hierarchical ZnO micro-flowers loaded with a new phase of face center cubic metallic Pt nanoparticles. The specific surface area was increased from 3.86 m<sup>2</sup> g<sup>–1</sup> for pure ZnO sample to 6.41 m<sup>2</sup> g<sup>–1</sup> for 0.5% Pt/ZnO nanocomposites, thus enhancing the photocatalytic performance. Photocatalytic activities of the samples were studied for the degradation of cationic methylene blue (MB) and anionic methyl orange (MO) dyes under UV light irradiation. The photocatalytic efficiencies of heterostructure 0.5% Pt/ZnO nanocomposites were the highest of 97.55 and 82.25% and were 2.51 and 3.07 times those of pure ZnO sample for MB and MO degradation under UV light irradiation, respectively. In this research, heterostructure 0.5% Pt/ZnO nanocomposites were excellently photostable and were the promising photocatalyst in practical application.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"99 4","pages":"808 - 820"},"PeriodicalIF":0.7000,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of ZnO Micro-flowers Loaded with Pt Nanoparticles Used As UV-Light-Driven Photocatalyst\",\"authors\":\"Anukorn Phuruangrat,&nbsp;Yothin Chimupala,&nbsp;Asanee Somdee,&nbsp;Titipun Thongtem,&nbsp;Somchai Thongtem\",\"doi\":\"10.1134/S0036024425700414\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>ZnO micro-flowers with and without the loaded 0.5–3.0% Pt nanoparticles as UV-light-driven photocatalyst were successfully prepared by microwave assisted-deposition method. The as-synthesized samples were composed of pure phase of wurtzite hexagonal ZnO micro-flowers the diameter of 3–5 μm and uniform hierarchical ZnO micro-flowers loaded with a new phase of face center cubic metallic Pt nanoparticles. The specific surface area was increased from 3.86 m<sup>2</sup> g<sup>–1</sup> for pure ZnO sample to 6.41 m<sup>2</sup> g<sup>–1</sup> for 0.5% Pt/ZnO nanocomposites, thus enhancing the photocatalytic performance. Photocatalytic activities of the samples were studied for the degradation of cationic methylene blue (MB) and anionic methyl orange (MO) dyes under UV light irradiation. The photocatalytic efficiencies of heterostructure 0.5% Pt/ZnO nanocomposites were the highest of 97.55 and 82.25% and were 2.51 and 3.07 times those of pure ZnO sample for MB and MO degradation under UV light irradiation, respectively. In this research, heterostructure 0.5% Pt/ZnO nanocomposites were excellently photostable and were the promising photocatalyst in practical application.</p>\",\"PeriodicalId\":767,\"journal\":{\"name\":\"Russian Journal of Physical Chemistry A\",\"volume\":\"99 4\",\"pages\":\"808 - 820\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2025-04-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Physical Chemistry A\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036024425700414\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024425700414","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

采用微波辅助沉积法成功制备了负载0.5 ~ 3.0% Pt纳米粒子和不负载0.5% ~ 3.0% Pt纳米粒子作为紫外光催化剂的ZnO微花。合成的样品由直径为3-5 μm的纯纤锌矿六方ZnO微花和加载新相的面心立方金属Pt纳米颗粒的均匀分层ZnO微花组成。比表面积从纯ZnO样品的3.86 m2 g-1增加到0.5% Pt/ZnO纳米复合材料的6.41 m2 g-1,从而提高了光催化性能。研究了样品在紫外光照射下对阳离子亚甲基蓝(MB)和阴离子甲基橙(MO)染料的光催化降解活性。在紫外光照射下,异质结构0.5% Pt/ZnO纳米复合材料降解MB和MO的光催化效率最高,分别为97.55%和82.25%,分别是纯ZnO样品的2.51和3.07倍。本研究制备的异质结构0.5% Pt/ZnO纳米复合材料具有良好的光稳定性,是一种具有实际应用前景的光催化剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and Characterization of ZnO Micro-flowers Loaded with Pt Nanoparticles Used As UV-Light-Driven Photocatalyst

ZnO micro-flowers with and without the loaded 0.5–3.0% Pt nanoparticles as UV-light-driven photocatalyst were successfully prepared by microwave assisted-deposition method. The as-synthesized samples were composed of pure phase of wurtzite hexagonal ZnO micro-flowers the diameter of 3–5 μm and uniform hierarchical ZnO micro-flowers loaded with a new phase of face center cubic metallic Pt nanoparticles. The specific surface area was increased from 3.86 m2 g–1 for pure ZnO sample to 6.41 m2 g–1 for 0.5% Pt/ZnO nanocomposites, thus enhancing the photocatalytic performance. Photocatalytic activities of the samples were studied for the degradation of cationic methylene blue (MB) and anionic methyl orange (MO) dyes under UV light irradiation. The photocatalytic efficiencies of heterostructure 0.5% Pt/ZnO nanocomposites were the highest of 97.55 and 82.25% and were 2.51 and 3.07 times those of pure ZnO sample for MB and MO degradation under UV light irradiation, respectively. In this research, heterostructure 0.5% Pt/ZnO nanocomposites were excellently photostable and were the promising photocatalyst in practical application.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
1.20
自引率
14.30%
发文量
376
审稿时长
5.1 months
期刊介绍: Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信