4/3-（甲氧基苯氧基）酞菁酸铜在氯仿中的溶解度和溶解热力学特征

IF 0.7 4区化学 Q4 CHEMISTRY, PHYSICAL

Russian Journal of Physical Chemistry A Pub Date : 2025-04-25 DOI:10.1134/S0036024425700268

A. E. Rassolova, G. R. Berezina, V. E. Maizlish

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引用次数: 0

摘要

作者研究了四-4和四-3取代的酞菁酸铜与邻位、间位或对苯酚片段在288 - 318k温度范围内的溶解度。化合物在氯仿中溶解的模式取决于取代基位于分子外围的位置。计算了合成金属配合物溶解的标准热力学参数。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Solubility and Thermodynamic Characteristics of Dissolution of Copper Tetra-4/3-(methoxyphenoxy)phthalocyaninates in Chloroform

The authors study the solubility of tetra-4- and tetra-3-substituted copper phthalocyaninates with fragments of ortho-, meta-, or pair- phenol in the temperature range 288–318 K. The patterns of dissolution of compounds in chloroform depending on the position of the substituent located on the periphery of the molecule are discussed. Standard thermodynamic parameters of dissolution of synthesized metal complexes are calculated.

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来源期刊

Russian Journal of Physical Chemistry A 化学-物理化学

CiteScore

1.20

自引率

14.30%

发文量

376

审稿时长

5.1 months

期刊介绍： Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.