{"title":"镍钴锰的回收及LiCo1/3Ni1/3Mn1/3O2正极材料的制备","authors":"Chunjie Liu, Qing Liu, Xuetian Li, Zhijiang Liu, Zhongcai Shao","doi":"10.1134/S0036024425700463","DOIUrl":null,"url":null,"abstract":"<p>Lithium-ion batteries have a limited lifespan, and disposing of them in large quantities can cause serious environmental problems. This study focused on the simulation of leaching solutions from waste ternary lithium battery cathode materials. A variety of precipitants were introduced with the objective of progressively leaching and separating valuable metals. The positive electrode material of LiNi<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>O<sub>2</sub> lithium-ion battery was synthesized by solid phase grinding. The charge-discharge capacity, cyclic stability, electrochemical impedance, and cyclic voltammetry of the prepared composites were analyzed. The results show that the initial charge-discharge ratio at 0.2 C is 171.7 mA h g<sup>–1</sup>, and the initial ratio increases to 65.87% after 50 cycles. The successful synthesis of ternary positive electrode materials proves the feasibility of preparing ternary positive electrode materials by solid phase grinding method and step separation method. It points out the development direction for the recycling and reuse of ternary cathode materials for waste lithium-ion batteries.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"99 4","pages":"871 - 878"},"PeriodicalIF":0.7000,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recovery of Nickel-Cobalt-Manganese and Preparation of LiCo1/3Ni1/3Mn1/3O2 Cathode Material\",\"authors\":\"Chunjie Liu, Qing Liu, Xuetian Li, Zhijiang Liu, Zhongcai Shao\",\"doi\":\"10.1134/S0036024425700463\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Lithium-ion batteries have a limited lifespan, and disposing of them in large quantities can cause serious environmental problems. This study focused on the simulation of leaching solutions from waste ternary lithium battery cathode materials. A variety of precipitants were introduced with the objective of progressively leaching and separating valuable metals. The positive electrode material of LiNi<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>O<sub>2</sub> lithium-ion battery was synthesized by solid phase grinding. The charge-discharge capacity, cyclic stability, electrochemical impedance, and cyclic voltammetry of the prepared composites were analyzed. The results show that the initial charge-discharge ratio at 0.2 C is 171.7 mA h g<sup>–1</sup>, and the initial ratio increases to 65.87% after 50 cycles. The successful synthesis of ternary positive electrode materials proves the feasibility of preparing ternary positive electrode materials by solid phase grinding method and step separation method. It points out the development direction for the recycling and reuse of ternary cathode materials for waste lithium-ion batteries.</p>\",\"PeriodicalId\":767,\"journal\":{\"name\":\"Russian Journal of Physical Chemistry A\",\"volume\":\"99 4\",\"pages\":\"871 - 878\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2025-04-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Physical Chemistry A\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036024425700463\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024425700463","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
锂离子电池寿命有限,大量废弃会造成严重的环境问题。对废旧三元锂电池正极材料的浸出溶液进行了模拟研究。介绍了多种沉淀剂,目的是逐步浸出和分离有价金属。采用固相研磨法制备了LiNi1/3Co1/3Mn1/3O2锂离子电池正极材料。对复合材料的充放电容量、循环稳定性、电化学阻抗和循环伏安特性进行了分析。结果表明:在0.2 C条件下,初始充放电比为171.7 mA h g-1,循环50次后,初始充放电比提高到65.87%;三元正极材料的成功合成证明了采用固相研磨法和阶梯分离法制备三元正极材料的可行性。指出了废锂离子电池三元正极材料回收再利用的发展方向。
Recovery of Nickel-Cobalt-Manganese and Preparation of LiCo1/3Ni1/3Mn1/3O2 Cathode Material
Lithium-ion batteries have a limited lifespan, and disposing of them in large quantities can cause serious environmental problems. This study focused on the simulation of leaching solutions from waste ternary lithium battery cathode materials. A variety of precipitants were introduced with the objective of progressively leaching and separating valuable metals. The positive electrode material of LiNi1/3Co1/3Mn1/3O2 lithium-ion battery was synthesized by solid phase grinding. The charge-discharge capacity, cyclic stability, electrochemical impedance, and cyclic voltammetry of the prepared composites were analyzed. The results show that the initial charge-discharge ratio at 0.2 C is 171.7 mA h g–1, and the initial ratio increases to 65.87% after 50 cycles. The successful synthesis of ternary positive electrode materials proves the feasibility of preparing ternary positive electrode materials by solid phase grinding method and step separation method. It points out the development direction for the recycling and reuse of ternary cathode materials for waste lithium-ion batteries.
期刊介绍:
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.