Umesh V. Shembade , Babasaheb T. Shinde , Mayuri G. Magadum , Sandeep B. Wategaonkar , Hemant V. Chavan , Mohammad Rafe Hatshan , Kulurumotlakatla Dasha Kumar , Annasaheb V. Moholkar
{"title":"基于二维g-C3N4复合电极材料的Fe2O3异质结构研究","authors":"Umesh V. Shembade , Babasaheb T. Shinde , Mayuri G. Magadum , Sandeep B. Wategaonkar , Hemant V. Chavan , Mohammad Rafe Hatshan , Kulurumotlakatla Dasha Kumar , Annasaheb V. Moholkar","doi":"10.1016/j.solidstatesciences.2025.107934","DOIUrl":null,"url":null,"abstract":"<div><div>Herein, we have studied fabricating high-performance based supercapacitors (SCs) using ferrite (Fe<sub>2</sub>O<sub>3</sub>) heterostructures which are anchored on two-dimensional graphitic nitrite (g-C<sub>3</sub>N<sub>4</sub>) via simple and low-cost chemical method for energy storage application. In this work, the Fe<sub>2</sub>O<sub>3</sub>, g-C<sub>3</sub>N<sub>4</sub>, and g-C<sub>3</sub>N<sub>4</sub>/Fe<sub>2</sub>O<sub>3</sub> composites were characterized using various physico-chemical techniques to analyze their crystal structures, stretching/bending vibrations, surface morphology, specific surface area, and the presence of the different electronic states, respectively. As a result, the prepared g-C<sub>3</sub>N<sub>4</sub>/Fe<sub>2</sub>O<sub>3</sub> composite exhibited a high specific capacitance and capacity of 1143 F/g and 254 mAh/g at a current density of 5 mA/cm<sup>2</sup> over other electrodes. However, the fabricated device reveals the maximum energy density of 33 Wh/kg and the power density of 3200 W/kg with superior electrochemical stability of 89 % over 5000 cycles. Based on the above results, the prepared g-C<sub>3</sub>N<sub>4</sub>/Fe<sub>2</sub>O<sub>3</sub> composites showed better flexibility, high supercapacitive performance, and a long lifetime stability. Therefore, this research opens up an exciting possibilities for developing advanced supercapacitor activities.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"164 ","pages":"Article 107934"},"PeriodicalIF":3.4000,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of Fe2O3 heterostructures anchored on 2D g-C3N4 composite electrode materials for supercapacitor activities\",\"authors\":\"Umesh V. Shembade , Babasaheb T. Shinde , Mayuri G. Magadum , Sandeep B. Wategaonkar , Hemant V. Chavan , Mohammad Rafe Hatshan , Kulurumotlakatla Dasha Kumar , Annasaheb V. Moholkar\",\"doi\":\"10.1016/j.solidstatesciences.2025.107934\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Herein, we have studied fabricating high-performance based supercapacitors (SCs) using ferrite (Fe<sub>2</sub>O<sub>3</sub>) heterostructures which are anchored on two-dimensional graphitic nitrite (g-C<sub>3</sub>N<sub>4</sub>) via simple and low-cost chemical method for energy storage application. In this work, the Fe<sub>2</sub>O<sub>3</sub>, g-C<sub>3</sub>N<sub>4</sub>, and g-C<sub>3</sub>N<sub>4</sub>/Fe<sub>2</sub>O<sub>3</sub> composites were characterized using various physico-chemical techniques to analyze their crystal structures, stretching/bending vibrations, surface morphology, specific surface area, and the presence of the different electronic states, respectively. As a result, the prepared g-C<sub>3</sub>N<sub>4</sub>/Fe<sub>2</sub>O<sub>3</sub> composite exhibited a high specific capacitance and capacity of 1143 F/g and 254 mAh/g at a current density of 5 mA/cm<sup>2</sup> over other electrodes. However, the fabricated device reveals the maximum energy density of 33 Wh/kg and the power density of 3200 W/kg with superior electrochemical stability of 89 % over 5000 cycles. Based on the above results, the prepared g-C<sub>3</sub>N<sub>4</sub>/Fe<sub>2</sub>O<sub>3</sub> composites showed better flexibility, high supercapacitive performance, and a long lifetime stability. Therefore, this research opens up an exciting possibilities for developing advanced supercapacitor activities.</div></div>\",\"PeriodicalId\":432,\"journal\":{\"name\":\"Solid State Sciences\",\"volume\":\"164 \",\"pages\":\"Article 107934\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2025-04-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solid State Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1293255825001128\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid State Sciences","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1293255825001128","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Development of Fe2O3 heterostructures anchored on 2D g-C3N4 composite electrode materials for supercapacitor activities
Herein, we have studied fabricating high-performance based supercapacitors (SCs) using ferrite (Fe2O3) heterostructures which are anchored on two-dimensional graphitic nitrite (g-C3N4) via simple and low-cost chemical method for energy storage application. In this work, the Fe2O3, g-C3N4, and g-C3N4/Fe2O3 composites were characterized using various physico-chemical techniques to analyze their crystal structures, stretching/bending vibrations, surface morphology, specific surface area, and the presence of the different electronic states, respectively. As a result, the prepared g-C3N4/Fe2O3 composite exhibited a high specific capacitance and capacity of 1143 F/g and 254 mAh/g at a current density of 5 mA/cm2 over other electrodes. However, the fabricated device reveals the maximum energy density of 33 Wh/kg and the power density of 3200 W/kg with superior electrochemical stability of 89 % over 5000 cycles. Based on the above results, the prepared g-C3N4/Fe2O3 composites showed better flexibility, high supercapacitive performance, and a long lifetime stability. Therefore, this research opens up an exciting possibilities for developing advanced supercapacitor activities.
期刊介绍:
Solid State Sciences is the journal for researchers from the broad solid state chemistry and physics community. It publishes key articles on all aspects of solid state synthesis, structure-property relationships, theory and functionalities, in relation with experiments.
Key topics for stand-alone papers and special issues:
-Novel ways of synthesis, inorganic functional materials, including porous and glassy materials, hybrid organic-inorganic compounds and nanomaterials
-Physical properties, emphasizing but not limited to the electrical, magnetical and optical features
-Materials related to information technology and energy and environmental sciences.
The journal publishes feature articles from experts in the field upon invitation.
Solid State Sciences - your gateway to energy-related materials.