锂离子电池新材料的设计:铝纳米颗粒辅助海藻基分离器

IF 1.6 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Sharon Mugobera, Kyuchul Lee, Jihyuk Jung, Inho Cho, Jang Myoun Ko, Kwang Se Lee
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引用次数: 0

摘要

隔膜是至关重要的部件,对电池的性能和安全性起着关键作用。本研究以红藻为原料制备了纤维素纳米纤维分离器。合成的纳米纤维素原纤维用于制备该分离器。并与商用聚乙烯(PE)分离器进行了电化学性能、热稳定性和形貌分析。所获得的紧密连接的纳米孔分离器在600次循环中显示出80%的容量保持率。由于羟基的存在增强了其优异的亲水性,它具有非常好的润湿性和离子导电性。由于Al2O3的存在,铝纳米颗粒辅助海藻基分离器(ASS)具有优异的物理性能,有助于其耐热性并保持其尺寸。与商用聚乙烯相比,它具有更高的电化学性能。在2C时,ASS的放电比容量为83 mAh/g, PE为77 mAh/g。然而,在低碳率下,两种分离器都表现出类似的结果。这项研究为生产一种有效的海藻基分离器提供了一种可行的选择,这种分离器用于锂离子电池的特殊物理性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Toward design of novel materials for lithium-ion batteries: Aluminium nanoparticle-assisted seaweed-based separator

Toward design of novel materials for lithium-ion batteries: Aluminium nanoparticle-assisted seaweed-based separator

Separators are a crucial component and play a pivotal role in battery performance and safety. In this study, a cellulose nanofibril separator was prepared from red algae. The generated nanosized cellulose fibrils were used in the preparation of the separator. The produced separator was analyzed for electrochemical performance, thermal stability, and morphology in comparison to the commercial polyethylene (PE) separator. The obtained densely linked nanoporous separator exhibited a capacity retention of 80% over 600 cycles. It had very good wettability and ionic conductivity results due to its excellent hydrophilic nature enhanced by the presence of the hydroxyl groups. The excellent physical properties of the aluminium nanoparticle-assisted seaweed-based separator (ASS) due to the presence of Al2O3, aided in its resilience to heat and maintained its dimensions. It exhibited greater electrochemical performance compared to the commercial PE. At 2C the discharge specific capacity was at 83 mAh/g for ASS and PE 77 mAh/g. However, the separators both exhibited comparable results at low C-rates. This study offers an achievable option for the production of an effective seaweed-based separator for use in lithium-ion batteries exceptional physical properties.

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来源期刊
CiteScore
3.40
自引率
11.10%
发文量
216
审稿时长
7.5 months
期刊介绍: The Journal of the Chinese Chemical Society was founded by The Chemical Society Located in Taipei in 1954, and is the oldest general chemistry journal in Taiwan. It is strictly peer-reviewed and welcomes review articles, full papers, notes and communications written in English. The scope of the Journal of the Chinese Chemical Society covers all major areas of chemistry: organic chemistry, inorganic chemistry, analytical chemistry, biochemistry, physical chemistry, and materials science.
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