回收混合塑料混合物的有用工具

IF 3.9 3区 化学 Q2 POLYMER SCIENCE
Sibele P. Cestari, Rafael V. dos Santos, Daniela F. S. Freitas, Rafael H. Cestari, Marcos L. Dias, Luis C. Mendes
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引用次数: 0

摘要

为了在循环经济中追求更可持续的做法,混合塑料混合物中聚合物含量的估计是必不可少的。本研究提出了一种测定再生塑料非均相混合物中聚丙烯(PP)和聚乙烯(PE)含量的简便方法。使用差示扫描量热数据建立了校准曲线,允许对PP和PE比率进行粗略估计。对7种再生PE/PP共混物进行了分析,观察了聚合物的交叉污染。用熔合焓和结晶度的线性拟合和二次拟合来估计聚合物的含量。结晶度的二次拟合最准确,PE的标准偏差为1.4%,PP的标准偏差为3.7%。该方法为小规模回收企业提高塑料回收效率提供了一种简单易行的工具,填补了聚烯烃更复杂的科学研究留下的空白。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A Useful Tool to Recycle Mixed Plastics Blends

A Useful Tool to Recycle Mixed Plastics Blends

In the pursuit of more sustainable practices within the circular economy, the estimation of polymer contents in mixed plastic blends is essential. This study presents a simple method for determining the polypropylene (PP) and polyethylene (PE) content in heterogeneous mixtures of recycled plastic. A calibration curve was developed using differential scanning calorimetry data, allowing for rough estimations of PP and PE ratios. Seven recycled PE/PP blends were analyzed, and cross-contamination of polymers was observed. Linear and quadratic fits of the enthalpy of fusion and degree of crystallinity were applied to estimate polymer contents. The quadratic fit of the degree of crystallinity provided the most accurate estimation, with standard deviations of 1.4% for PE and 3.7% for PP. This method offers a simple and accessible tool for small-scale recyclers to improve the efficiency of plastic recycling, filling a gap left by more complex scientific studies on polyolefins.

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来源期刊
Journal of Polymer Science
Journal of Polymer Science POLYMER SCIENCE-
CiteScore
6.30
自引率
5.90%
发文量
264
期刊介绍: Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology.
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