四-4（4-甲氧基苯氧基）酞菁与含氮有机碱酸碱相互作用的反应性

IF 0.7 4区化学 Q4 CHEMISTRY, PHYSICAL

Russian Journal of Physical Chemistry A Pub Date : 2025-04-14 DOI:10.1134/S0036024424703485

O. A. Petrov

{"title":"四-4（4-甲氧基苯氧基）酞菁与含氮有机碱酸碱相互作用的反应性","authors":"O. A. Petrov","doi":"10.1134/S0036024424703485","DOIUrl":null,"url":null,"abstract":"The interactions of tetra-4(4-methoxyphenoxy)phthalocyanine with pyridine, 2-methylpyridine, morpholine, piperidine, n-butylamine, tert-butylamine, diethylamine, and triethylamine in benzene and benzene–dimethylsulfoxide system have been studied. The acid-base reaction is an unusually slow process that forms proton transfer complexes that are stable over time. Their structure is proposed. The change in the reactivity of tetra-4(4-methoxyphenoxy)phthalocyanine depending on the polarity of the medium, proton-acceptor capacity, and spatial structure of the nitrogen-containing base is considered.","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"99 3","pages":"446 - 452"},"PeriodicalIF":0.7000,"publicationDate":"2025-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Reactivity of Tetra-4(4-methoxyphenoxy)phthalocyanine in Acid-Base Interactions with Nitrogen-Containing Organic Bases\",\"authors\":\"O. A. Petrov\",\"doi\":\"10.1134/S0036024424703485\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The interactions of tetra-4(4-methoxyphenoxy)phthalocyanine with pyridine, 2-methylpyridine, morpholine, piperidine, n-butylamine, tert-butylamine, diethylamine, and triethylamine in benzene and benzene–dimethylsulfoxide system have been studied. The acid-base reaction is an unusually slow process that forms proton transfer complexes that are stable over time. Their structure is proposed. The change in the reactivity of tetra-4(4-methoxyphenoxy)phthalocyanine depending on the polarity of the medium, proton-acceptor capacity, and spatial structure of the nitrogen-containing base is considered.\",\"PeriodicalId\":767,\"journal\":{\"name\":\"Russian Journal of Physical Chemistry A\",\"volume\":\"99 3\",\"pages\":\"446 - 452\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2025-04-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Physical Chemistry A\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036024424703485\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024424703485","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

摘要

研究了四-4（4-甲氧基苯氧基）酞菁与吡啶、2-甲基吡啶、啉、哌啶、正丁胺、叔丁胺、二乙胺和三乙胺在苯和苯-二甲基亚砜体系中的相互作用。酸碱反应是一个异常缓慢的过程，形成质子转移复合物，随着时间的推移是稳定的。提出了它们的结构。考虑了四-4（4-甲氧基苯氧基）酞菁的反应活性随介质极性、质子受体容量和含氮碱的空间结构的变化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Reactivity of Tetra-4(4-methoxyphenoxy)phthalocyanine in Acid-Base Interactions with Nitrogen-Containing Organic Bases

The interactions of tetra-4(4-methoxyphenoxy)phthalocyanine with pyridine, 2-methylpyridine, morpholine, piperidine, n-butylamine, tert-butylamine, diethylamine, and triethylamine in benzene and benzene–dimethylsulfoxide system have been studied. The acid-base reaction is an unusually slow process that forms proton transfer complexes that are stable over time. Their structure is proposed. The change in the reactivity of tetra-4(4-methoxyphenoxy)phthalocyanine depending on the polarity of the medium, proton-acceptor capacity, and spatial structure of the nitrogen-containing base is considered.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Russian Journal of Physical Chemistry A 化学-物理化学

CiteScore

1.20

自引率

14.30%

发文量

376

审稿时长

5.1 months

期刊介绍： Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.