碱金属卤化物两相熔体的附着力

IF 0.7 4区化学 Q4 CHEMISTRY, PHYSICAL

Russian Journal of Physical Chemistry A Pub Date : 2025-04-14 DOI:10.1134/S003602442470362X

V. P. Stepanov

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引用次数: 0

摘要

文章主要分析了两相熔体 LiF + KBr、LiF + CsCl、LiF + RbBr、LiF + KI、LiF + CsBr、LiF + RbI、LiF + CsI 中各相的粘附作用。研究发现，由于离子的热运动和共存相成分变化的叠加作用，相的附着力随着温度的升高而增加。当各组分不相溶的浓度范围变宽时，相的附着力会减小。在相同温度下，相粘附性随着混合离子大小差异的减小而增加。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Adhesion in Two-Phase Melts of Alkali Metal Halides

The article is devoted to the analysis of adhesive interaction of phases in two-phase melts LiF + KBr, LiF + CsCl, LiF + RbBr, LiF + KI, LiF + CsBr, LiF + RbI, LiF + CsI. It was established that the adhesion of phases increases with increasing temperature as a result of the superposition of the thermal motion of ions and changes in the compositions of the coexisting phases. The adhesion of phases decreases when the concentration range of immiscibility of components becomes wider. At the same temperature, phase adhesion increases with decreasing difference in the sizes of the mixed ions.

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来源期刊

Russian Journal of Physical Chemistry A 化学-物理化学

CiteScore

1.20

自引率

14.30%

发文量

376

审稿时长

5.1 months

期刊介绍： Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.