Azulene-Fused - seco- hexab并冠烯基纳米石墨烯

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-04-14 DOI:10.1021/acs.orglett.5c01292

Haifan Zhang, Peng An

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引用次数: 0

摘要

由于其独特的电子结构，含氮多环芳烃在调整苯类碳环系统的化学和电子特性方面备受关注。在此，我们报告了两类仲六苯并呋喃基氮杂环烯的合成和性质。X 射线晶体学分析表明，这两种纳米石墨烯为非平面结构，在固体结构中具有高度扭转的外围。实验和计算研究表明，这些纳米石墨烯具有典型的窄最高占位分子轨道-最低未占位分子轨道（HOMO-LUMO）能隙、长波长吸收和反卡沙发射。有趣的是，这些纳米石墨烯表现出明显的光热效应。

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Azulene-Fused seco-Hexabenzocoronene-Based Nanographenes

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Azulene-Fused seco-Hexabenzocoronene-Based Nanographenes

Due to the unique electronic structure, azulene-containing polycyclic aromatic hydrocarbons attract significant attention toward tuning the chemical and electronic properties of benzenoid carbocyclic systems. Here, we report the synthesis and properties of two types of azulene fused, seco-hexabenzocoronene-based nanographenes. The X-ray crystallographic analysis indicated their nonplanar structures with highly torsional periphery in the solid structures. The typical narrow highest occupied molecular orbital–lowest unoccupied molecular orbital (HOMO–LUMO) energy gaps, long-wavelength absorption, and anti-Kasha emissions were investigated by experimental and computational studies. Interestingly, these nanographenes exhibited a pronounced photothermal effect.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.