{"title":"光浸泡对富fa混合卤化物双、三阳离子钙钛矿吸收层和高效倒p-i-n钙钛矿太阳能电池的影响","authors":"Tanwistha Chakrabarti, and , Ajay Perumal*, ","doi":"10.1021/acsaem.5c0015210.1021/acsaem.5c00152","DOIUrl":null,"url":null,"abstract":"<p >Light soaking (under continuous light exposure) significantly affects the optical and electronic properties of perovskite absorbers, affecting solar cell performance over time. This study examines the effects of light soaking on two mixed-halide, mixed-cation perovskite absorber layers, namely Cs<sub>0.17</sub>FA<sub>0.83</sub>Pb(I<sub>0.9</sub>Br<sub>0.1</sub>)<sub>3</sub> (CsFA) and Cs<sub>0.05</sub>(FA<sub>0.83</sub>MA<sub>0.17</sub>)<sub>0.95</sub>Pb(I<sub>0.9</sub>Br<sub>0.1</sub>)<sub>3</sub> (CsMAFA) in thin films and solar cells. Optimized CsFA and CsMAFA solar cell devices achieve PCEs of 17.1% and 18.8%, respectively. Under continuous illumination, CsMAFA devices show faster stabilization of open-circuit voltage (<i>V</i><sub>OC</sub>), indicating efficient charge separation and reduced non-radiative recombination. The steady-state and time-resolved photoluminescence (PL and TRPL) measurements suggest that MA reduces defect-induced recombination in CsMAFA, while both bulk and interfacial defects contribute in CsFA. Impedance measurements reveal better-aligned trap states in CsMAFA, facilitating faster charge collection and lower recombination losses, whereas CsFA exhibits slower response and higher recombination.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 7","pages":"4554–4563 4554–4563"},"PeriodicalIF":5.4000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Light Soaking on FA-Rich Mixed Halide Double and Triple Cation Perovskite Absorber Layers and Efficient Inverted p–i–n Perovskite Solar Cells\",\"authors\":\"Tanwistha Chakrabarti, and , Ajay Perumal*, \",\"doi\":\"10.1021/acsaem.5c0015210.1021/acsaem.5c00152\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Light soaking (under continuous light exposure) significantly affects the optical and electronic properties of perovskite absorbers, affecting solar cell performance over time. This study examines the effects of light soaking on two mixed-halide, mixed-cation perovskite absorber layers, namely Cs<sub>0.17</sub>FA<sub>0.83</sub>Pb(I<sub>0.9</sub>Br<sub>0.1</sub>)<sub>3</sub> (CsFA) and Cs<sub>0.05</sub>(FA<sub>0.83</sub>MA<sub>0.17</sub>)<sub>0.95</sub>Pb(I<sub>0.9</sub>Br<sub>0.1</sub>)<sub>3</sub> (CsMAFA) in thin films and solar cells. Optimized CsFA and CsMAFA solar cell devices achieve PCEs of 17.1% and 18.8%, respectively. Under continuous illumination, CsMAFA devices show faster stabilization of open-circuit voltage (<i>V</i><sub>OC</sub>), indicating efficient charge separation and reduced non-radiative recombination. The steady-state and time-resolved photoluminescence (PL and TRPL) measurements suggest that MA reduces defect-induced recombination in CsMAFA, while both bulk and interfacial defects contribute in CsFA. Impedance measurements reveal better-aligned trap states in CsMAFA, facilitating faster charge collection and lower recombination losses, whereas CsFA exhibits slower response and higher recombination.</p>\",\"PeriodicalId\":4,\"journal\":{\"name\":\"ACS Applied Energy Materials\",\"volume\":\"8 7\",\"pages\":\"4554–4563 4554–4563\"},\"PeriodicalIF\":5.4000,\"publicationDate\":\"2025-03-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Energy Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsaem.5c00152\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Energy Materials","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsaem.5c00152","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Influence of Light Soaking on FA-Rich Mixed Halide Double and Triple Cation Perovskite Absorber Layers and Efficient Inverted p–i–n Perovskite Solar Cells
Light soaking (under continuous light exposure) significantly affects the optical and electronic properties of perovskite absorbers, affecting solar cell performance over time. This study examines the effects of light soaking on two mixed-halide, mixed-cation perovskite absorber layers, namely Cs0.17FA0.83Pb(I0.9Br0.1)3 (CsFA) and Cs0.05(FA0.83MA0.17)0.95Pb(I0.9Br0.1)3 (CsMAFA) in thin films and solar cells. Optimized CsFA and CsMAFA solar cell devices achieve PCEs of 17.1% and 18.8%, respectively. Under continuous illumination, CsMAFA devices show faster stabilization of open-circuit voltage (VOC), indicating efficient charge separation and reduced non-radiative recombination. The steady-state and time-resolved photoluminescence (PL and TRPL) measurements suggest that MA reduces defect-induced recombination in CsMAFA, while both bulk and interfacial defects contribute in CsFA. Impedance measurements reveal better-aligned trap states in CsMAFA, facilitating faster charge collection and lower recombination losses, whereas CsFA exhibits slower response and higher recombination.
期刊介绍：
ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
