{"title":"用van Deemter方程表征TCAP的Pd/k介质","authors":"J.R. Hanby , S. Silliman , W.T. Shmayda","doi":"10.1016/j.fusengdes.2025.115001","DOIUrl":null,"url":null,"abstract":"<div><div>TCAP, or thermal cycling absorption process, is a method for separating hydrogen isotopes using the selective absorption properties of a medium, such as palladium. In order to characterize the efficiency of the medium, we performed pulse tests of deuterium into a flow of hydrogen over the range of superficial velocities from 0.5 to <span><math><mrow><mn>7</mn><mi>c</mi><mi>m</mi><mo>/</mo><mi>s</mi></mrow></math></span> and used the responses to generate van Deemter curves for four temperatures; <span><math><mrow><mn>77</mn><mi>K</mi></mrow></math></span>, <span><math><mrow><mn>195</mn><mi>K</mi></mrow></math></span>, <span><math><mrow><mn>295</mn><mi>K</mi></mrow></math></span>, and <span><math><mrow><mn>373</mn><mi>K</mi></mrow></math></span>. We found that the <span><math><mrow><mn>77</mn><mi>K</mi></mrow></math></span> runs exhibited the shortest Height Equivalent to a Theoretical Plate (HETP) values while at <span><math><mrow><mn>373</mn><mi>K</mi></mrow></math></span> the HETP values were longer by a factor of around 3.</div></div>","PeriodicalId":55133,"journal":{"name":"Fusion Engineering and Design","volume":"216 ","pages":"Article 115001"},"PeriodicalIF":1.9000,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Characterization of Pd/k medium for TCAP using van Deemter equation\",\"authors\":\"J.R. Hanby , S. Silliman , W.T. Shmayda\",\"doi\":\"10.1016/j.fusengdes.2025.115001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>TCAP, or thermal cycling absorption process, is a method for separating hydrogen isotopes using the selective absorption properties of a medium, such as palladium. In order to characterize the efficiency of the medium, we performed pulse tests of deuterium into a flow of hydrogen over the range of superficial velocities from 0.5 to <span><math><mrow><mn>7</mn><mi>c</mi><mi>m</mi><mo>/</mo><mi>s</mi></mrow></math></span> and used the responses to generate van Deemter curves for four temperatures; <span><math><mrow><mn>77</mn><mi>K</mi></mrow></math></span>, <span><math><mrow><mn>195</mn><mi>K</mi></mrow></math></span>, <span><math><mrow><mn>295</mn><mi>K</mi></mrow></math></span>, and <span><math><mrow><mn>373</mn><mi>K</mi></mrow></math></span>. We found that the <span><math><mrow><mn>77</mn><mi>K</mi></mrow></math></span> runs exhibited the shortest Height Equivalent to a Theoretical Plate (HETP) values while at <span><math><mrow><mn>373</mn><mi>K</mi></mrow></math></span> the HETP values were longer by a factor of around 3.</div></div>\",\"PeriodicalId\":55133,\"journal\":{\"name\":\"Fusion Engineering and Design\",\"volume\":\"216 \",\"pages\":\"Article 115001\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2025-04-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fusion Engineering and Design\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0920379625002017\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"NUCLEAR SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fusion Engineering and Design","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0920379625002017","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"NUCLEAR SCIENCE & TECHNOLOGY","Score":null,"Total":0}
Characterization of Pd/k medium for TCAP using van Deemter equation
TCAP, or thermal cycling absorption process, is a method for separating hydrogen isotopes using the selective absorption properties of a medium, such as palladium. In order to characterize the efficiency of the medium, we performed pulse tests of deuterium into a flow of hydrogen over the range of superficial velocities from 0.5 to and used the responses to generate van Deemter curves for four temperatures; , , , and . We found that the runs exhibited the shortest Height Equivalent to a Theoretical Plate (HETP) values while at the HETP values were longer by a factor of around 3.
期刊介绍:
The journal accepts papers about experiments (both plasma and technology), theory, models, methods, and designs in areas relating to technology, engineering, and applied science aspects of magnetic and inertial fusion energy. Specific areas of interest include: MFE and IFE design studies for experiments and reactors; fusion nuclear technologies and materials, including blankets and shields; analysis of reactor plasmas; plasma heating, fuelling, and vacuum systems; drivers, targets, and special technologies for IFE, controls and diagnostics; fuel cycle analysis and tritium reprocessing and handling; operations and remote maintenance of reactors; safety, decommissioning, and waste management; economic and environmental analysis of components and systems.