Tiago Valim Angelo , Christopher J. Spencer , Hong-Yan Li , Derek Knaack , Ziyi Zhu , Marina Seraine , Nick M.W. Roberts , Evelyne Leduc , Sophie Divilek , Anna Ren , Brian Joy , Gui-Mei Lu
{"title":"生物成因和锰铁沉积物的俯冲和熔融,以亚莫霍花岗岩类为证","authors":"Tiago Valim Angelo , Christopher J. Spencer , Hong-Yan Li , Derek Knaack , Ziyi Zhu , Marina Seraine , Nick M.W. Roberts , Evelyne Leduc , Sophie Divilek , Anna Ren , Brian Joy , Gui-Mei Lu","doi":"10.1016/j.chemgeo.2025.122759","DOIUrl":null,"url":null,"abstract":"<div><div>Mantle-hosted granitoids (MHG) from the supra-subduction Samail ophiolite in Oman and the United Arab Emirates exhibit diverse compositions, highlighting variations in petrogenesis and source contributions. Previous isotopic data indicate these MHG originated through the interaction of sediment-derived with basaltic melts from an underthrust oceanic plate within the mantle wedge. The sedimentary contribution was attributed to the partial melting of pelitic to siliceous (bio-siliceous) material atop the subducted plate based on elevated zircon δ<sup>18</sup>O values (∼14–28 ‰). To further evaluate this hypothesis on Samail MHG petrogenesis and source contribution, we present new and compiled radiogenic (Sr-Nd-Hf-Pb) and stable (O-Li-H) isotopes, along with zircon trace element analyses. The variable Sr and Pb isotopic signature support a mixed origin involving altered mafic and sedimentary sources in the formation of the MHG. Negative whole-rock εNd, coupled with elevated δ<sup>7</sup>Li in muscovite suggest the involvement of sedimentary sources and particularly those resembling deep-sea ferromanganese-rich sediments. We propose a new model identifying ferromanganese sediments as a potential source given their widespread distribution across the ocean floor, broad range of δ<sup>18</sup>O (up to 29.5 ‰), slightly positive Hf values, seawater-like δ<sup>7</sup>Li signatures (median of ∼27 ‰), and zircon trace element compositions lacking a signature of monazite co-precipitation, which match the signatures required for the genesis of the Samail MHG. Preservation of oceanic lithosphere in the geological record is limited, and MHG in ophiolites are uncommon. Therefore, the Samail MHG are key examples of crustal materials transported to the mantle, with implications for mantle heterogeneity and arc mantle redox budget.</div></div>","PeriodicalId":9847,"journal":{"name":"Chemical Geology","volume":"683 ","pages":"Article 122759"},"PeriodicalIF":3.6000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Subduction and melting of biogenic and ferromanganese sediments as evidenced by sub-Moho granitoids\",\"authors\":\"Tiago Valim Angelo , Christopher J. Spencer , Hong-Yan Li , Derek Knaack , Ziyi Zhu , Marina Seraine , Nick M.W. Roberts , Evelyne Leduc , Sophie Divilek , Anna Ren , Brian Joy , Gui-Mei Lu\",\"doi\":\"10.1016/j.chemgeo.2025.122759\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Mantle-hosted granitoids (MHG) from the supra-subduction Samail ophiolite in Oman and the United Arab Emirates exhibit diverse compositions, highlighting variations in petrogenesis and source contributions. Previous isotopic data indicate these MHG originated through the interaction of sediment-derived with basaltic melts from an underthrust oceanic plate within the mantle wedge. The sedimentary contribution was attributed to the partial melting of pelitic to siliceous (bio-siliceous) material atop the subducted plate based on elevated zircon δ<sup>18</sup>O values (∼14–28 ‰). To further evaluate this hypothesis on Samail MHG petrogenesis and source contribution, we present new and compiled radiogenic (Sr-Nd-Hf-Pb) and stable (O-Li-H) isotopes, along with zircon trace element analyses. The variable Sr and Pb isotopic signature support a mixed origin involving altered mafic and sedimentary sources in the formation of the MHG. Negative whole-rock εNd, coupled with elevated δ<sup>7</sup>Li in muscovite suggest the involvement of sedimentary sources and particularly those resembling deep-sea ferromanganese-rich sediments. We propose a new model identifying ferromanganese sediments as a potential source given their widespread distribution across the ocean floor, broad range of δ<sup>18</sup>O (up to 29.5 ‰), slightly positive Hf values, seawater-like δ<sup>7</sup>Li signatures (median of ∼27 ‰), and zircon trace element compositions lacking a signature of monazite co-precipitation, which match the signatures required for the genesis of the Samail MHG. Preservation of oceanic lithosphere in the geological record is limited, and MHG in ophiolites are uncommon. 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Subduction and melting of biogenic and ferromanganese sediments as evidenced by sub-Moho granitoids
Mantle-hosted granitoids (MHG) from the supra-subduction Samail ophiolite in Oman and the United Arab Emirates exhibit diverse compositions, highlighting variations in petrogenesis and source contributions. Previous isotopic data indicate these MHG originated through the interaction of sediment-derived with basaltic melts from an underthrust oceanic plate within the mantle wedge. The sedimentary contribution was attributed to the partial melting of pelitic to siliceous (bio-siliceous) material atop the subducted plate based on elevated zircon δ18O values (∼14–28 ‰). To further evaluate this hypothesis on Samail MHG petrogenesis and source contribution, we present new and compiled radiogenic (Sr-Nd-Hf-Pb) and stable (O-Li-H) isotopes, along with zircon trace element analyses. The variable Sr and Pb isotopic signature support a mixed origin involving altered mafic and sedimentary sources in the formation of the MHG. Negative whole-rock εNd, coupled with elevated δ7Li in muscovite suggest the involvement of sedimentary sources and particularly those resembling deep-sea ferromanganese-rich sediments. We propose a new model identifying ferromanganese sediments as a potential source given their widespread distribution across the ocean floor, broad range of δ18O (up to 29.5 ‰), slightly positive Hf values, seawater-like δ7Li signatures (median of ∼27 ‰), and zircon trace element compositions lacking a signature of monazite co-precipitation, which match the signatures required for the genesis of the Samail MHG. Preservation of oceanic lithosphere in the geological record is limited, and MHG in ophiolites are uncommon. Therefore, the Samail MHG are key examples of crustal materials transported to the mantle, with implications for mantle heterogeneity and arc mantle redox budget.
期刊介绍:
Chemical Geology is an international journal that publishes original research papers on isotopic and elemental geochemistry, geochronology and cosmochemistry.
The Journal focuses on chemical processes in igneous, metamorphic, and sedimentary petrology, low- and high-temperature aqueous solutions, biogeochemistry, the environment and cosmochemistry.
Papers that are field, experimentally, or computationally based are appropriate if they are of broad international interest. The Journal generally does not publish papers that are primarily of regional or local interest, or which are primarily focused on remediation and applied geochemistry.
The Journal also welcomes innovative papers dealing with significant analytical advances that are of wide interest in the community and extend significantly beyond the scope of what would be included in the methods section of a standard research paper.