在有机合成和其他应用中使用深共晶溶剂的最新进展和新趋势

IF 5.3 2区 化学 Q2 CHEMISTRY, PHYSICAL
Hossein Tavakol , Parvaneh Shafieyoon
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引用次数: 0

摘要

本文综述了深共晶溶剂(DESs)在不同学科中的分类应用。近几十年来,DESs因其易得性好、成本低、对有机和无机化合物具有良好的溶解度、具有溶剂和催化剂的双重作用、耐高温以及进行反应、预处理和分离步骤简单而成为有机反应中最重要的反应介质。根据以前的报道,它们已广泛应用于分离、提取、制药、生物燃料、生物科学和聚合物技术。通过对现有文献的详细回顾,发现缺乏一个全面的综述来展示这类化合物的大多数报道方面,重点关注这一领域的最新进展和新趋势。这份报告很有用,它为从事该领域每一类研究的科学家展示了路线图。为了增进对发展决策系统在每个领域的效力的了解,表中列出了应用的简要清单,并讨论了最重要的主题。目前的工作确定了未来在这一领域进行研究的潜在领域,以及与发展经济资料的使用有关的最感兴趣的题目。此外,它还涵盖了在各个领域使用发展资料的最新发展,以区分空白,这可以在今后的研究中加以制定。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Recent advances and new trends in the use of deep eutectic solvents in organic synthesis and other applications

Recent advances and new trends in the use of deep eutectic solvents in organic synthesis and other applications
In this report, the classified applications of deep eutectic solvents (DESs) in different disciplines have been reviewed. DESs have been the most important reaction media for organic reactions during last decades because of their availability, low cost, promising solubility of organic and inorganic compounds, playing dual roles of solvent and catalyst, high temperature tolerance and simple procedure for performing reaction, work-up, and separations steps. Based on the previous reports, they have been vastly employed in separation, extraction, pharmaceuticals, biofuels, biological science and polymer technology. A detailed review of the current literature reveals the lack of a comprehensive review to show the most reported aspects of this class of compounds, focusing on the recent advances and new trends in this area. This report is useful to show the road map for the scientists who do research in each category of this area. To enhance the understanding the potencies of DESs, in each field, a brief list of applications was showed in the table, as well as discussing about the most important topics. The present work identifies potential areas for future studies in this field and the most interested topics related to the use of DESs. Moreover, it covers recent developments in the use of DESs in various field to distinguish the empty spaces, which could be worked out in the future studies.
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来源期刊
Journal of Molecular Liquids
Journal of Molecular Liquids 化学-物理:原子、分子和化学物理
CiteScore
10.30
自引率
16.70%
发文量
2597
审稿时长
78 days
期刊介绍: The journal includes papers in the following areas: – Simple organic liquids and mixtures – Ionic liquids – Surfactant solutions (including micelles and vesicles) and liquid interfaces – Colloidal solutions and nanoparticles – Thermotropic and lyotropic liquid crystals – Ferrofluids – Water, aqueous solutions and other hydrogen-bonded liquids – Lubricants, polymer solutions and melts – Molten metals and salts – Phase transitions and critical phenomena in liquids and confined fluids – Self assembly in complex liquids.– Biomolecules in solution The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include: – Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.) – Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.) – Light scattering (Rayleigh, Brillouin, PCS, etc.) – Dielectric relaxation – X-ray and neutron scattering and diffraction. Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.
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