{"title":"在有机合成和其他应用中使用深共晶溶剂的最新进展和新趋势","authors":"Hossein Tavakol , Parvaneh Shafieyoon","doi":"10.1016/j.molliq.2025.127510","DOIUrl":null,"url":null,"abstract":"<div><div>In this report, the classified applications of deep eutectic solvents (DESs) in different disciplines have been reviewed. DESs have been the most important reaction media for organic reactions during last decades because of their availability, low cost, promising solubility of organic and inorganic compounds, playing dual roles of solvent and catalyst, high temperature tolerance and simple procedure for performing reaction, work-up, and separations steps. Based on the previous reports, they have been vastly employed in separation, extraction, pharmaceuticals, biofuels, biological science and polymer technology. A detailed review of the current literature reveals the lack of a comprehensive review to show the most reported aspects of this class of compounds, focusing on the recent advances and new trends in this area. This report is useful to show the road map for the scientists who do research in each category of this area. To enhance the understanding the potencies of DESs, in each field, a brief list of applications was showed in the table, as well as discussing about the most important topics. The present work identifies potential areas for future studies in this field and the most interested topics related to the use of DESs. Moreover, it covers recent developments in the use of DESs in various field to distinguish the empty spaces, which could be worked out in the future studies.</div></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":"428 ","pages":"Article 127510"},"PeriodicalIF":5.3000,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent advances and new trends in the use of deep eutectic solvents in organic synthesis and other applications\",\"authors\":\"Hossein Tavakol , Parvaneh Shafieyoon\",\"doi\":\"10.1016/j.molliq.2025.127510\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this report, the classified applications of deep eutectic solvents (DESs) in different disciplines have been reviewed. DESs have been the most important reaction media for organic reactions during last decades because of their availability, low cost, promising solubility of organic and inorganic compounds, playing dual roles of solvent and catalyst, high temperature tolerance and simple procedure for performing reaction, work-up, and separations steps. Based on the previous reports, they have been vastly employed in separation, extraction, pharmaceuticals, biofuels, biological science and polymer technology. A detailed review of the current literature reveals the lack of a comprehensive review to show the most reported aspects of this class of compounds, focusing on the recent advances and new trends in this area. This report is useful to show the road map for the scientists who do research in each category of this area. To enhance the understanding the potencies of DESs, in each field, a brief list of applications was showed in the table, as well as discussing about the most important topics. The present work identifies potential areas for future studies in this field and the most interested topics related to the use of DESs. Moreover, it covers recent developments in the use of DESs in various field to distinguish the empty spaces, which could be worked out in the future studies.</div></div>\",\"PeriodicalId\":371,\"journal\":{\"name\":\"Journal of Molecular Liquids\",\"volume\":\"428 \",\"pages\":\"Article 127510\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2025-04-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Molecular Liquids\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0167732225006774\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Molecular Liquids","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167732225006774","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Recent advances and new trends in the use of deep eutectic solvents in organic synthesis and other applications
In this report, the classified applications of deep eutectic solvents (DESs) in different disciplines have been reviewed. DESs have been the most important reaction media for organic reactions during last decades because of their availability, low cost, promising solubility of organic and inorganic compounds, playing dual roles of solvent and catalyst, high temperature tolerance and simple procedure for performing reaction, work-up, and separations steps. Based on the previous reports, they have been vastly employed in separation, extraction, pharmaceuticals, biofuels, biological science and polymer technology. A detailed review of the current literature reveals the lack of a comprehensive review to show the most reported aspects of this class of compounds, focusing on the recent advances and new trends in this area. This report is useful to show the road map for the scientists who do research in each category of this area. To enhance the understanding the potencies of DESs, in each field, a brief list of applications was showed in the table, as well as discussing about the most important topics. The present work identifies potential areas for future studies in this field and the most interested topics related to the use of DESs. Moreover, it covers recent developments in the use of DESs in various field to distinguish the empty spaces, which could be worked out in the future studies.
期刊介绍:
The journal includes papers in the following areas:
– Simple organic liquids and mixtures
– Ionic liquids
– Surfactant solutions (including micelles and vesicles) and liquid interfaces
– Colloidal solutions and nanoparticles
– Thermotropic and lyotropic liquid crystals
– Ferrofluids
– Water, aqueous solutions and other hydrogen-bonded liquids
– Lubricants, polymer solutions and melts
– Molten metals and salts
– Phase transitions and critical phenomena in liquids and confined fluids
– Self assembly in complex liquids.– Biomolecules in solution
The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include:
– Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.)
– Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.)
– Light scattering (Rayleigh, Brillouin, PCS, etc.)
– Dielectric relaxation
– X-ray and neutron scattering and diffraction.
Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.