亚胺膦酰胺的综合配位化学

IF 6.1 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Frontiers Pub Date : 2025-04-09 DOI:10.1039/d5qi00275c

Bhupendra Goswami, Peter W. Roesky

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引用次数: 0

摘要

亚磷酰胺[R2P(NR ')2] -配体是磷酸盐（R2PO2 -）的类似物，用两个酰胺基团取代其氧原子。本文综述了亚氨基膦酰胺配体的配位化学研究进展，重点介绍了s-嵌段、p-嵌段、过渡和f-嵌段金属。特别讨论了这种单阴离子配体的配位方式和与金属中心的反应性。回顾的最后一部分致力于报道手性亚胺膦胺配体和相应的金属配合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Comprehensive coordination chemistry of iminophosphonamides

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Comprehensive coordination chemistry of iminophosphonamides

The iminophosphonamide [R₂P(NR′)₂]⁻ ligand is an analog of phosphate (R₂PO₂⁻), replacing its oxygen atoms with two amide groups. This review aims to provide the first comprehensive report on coordination chemistry dealing with iminophosphonamide ligands, focusing on the s-block, p-block, transition, and f-block metals. In particular, this monoanionic ligand's coordination mode and reactivity with the metal centers are discussed. The last section of the review is dedicated to the reported chiral iminophosphonamine ligands and corresponding metal complexes.

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