Photothermal spectroscopy for planetary sciences: Mid-IR absorption made easy

The understanding of the formation and evolution of the solar system still has many unanswered questions. Formation of solids in the solar system, mineral and organic mixing, and planetary body creation are all topics of interest to the community. Studying these phenomena is often performed through observations, remote sensing, and in-situ analysis, but there are limitations to the methods. Limitations such as IR diffraction limits, spatial resolution issues, and spectral resolution issues can prevent detection of organics, detection and identification of cellular structures, and the disentangling of granular mixtures. Optical-PhotoThermal InfraRed (O-PTIR) spectroscopy is a relatively new method of spectroscopy currently used in fields other than planetary sciences. O-PTIR is a non-destructive, highly repeatable, and fast form of measurement capable of reducing these limitations. Using a dual laser system with an IR source tuned to the mid-IR wavelength we performed laboratory O-PTIR measurements to compare O-PTIR data to existing IR absorption data and laboratory FTIR measurements for planetary materials. We do this for the purpose of introducing O-PTIR to the planetary science community. The technique featured here would serve to better measurements of planetary bodies during in-situ analysis. This is due to the technique’s ability to match absorption features in the mid-IR while performing non-contact analysis at a sub-micron level. We find that for the materials discussed in this work, O-PTIR was capable of identifying materials when utilizing known features and peaks of comparable absorption spectra.