“二维钴二硫烯金属-有机骨架中的金属导电性”的撤回

IF 15.6 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Andrew J. Clough, Jonathan M. Skelton, Courtney A. Downes, Ashley A. de la Rosa, Joseph W. Yoo, Aron Walsh, Brent C. Melot, Smaranda C. Marinescu
{"title":"“二维钴二硫烯金属-有机骨架中的金属导电性”的撤回","authors":"Andrew J. Clough, Jonathan M. Skelton, Courtney A. Downes, Ashley A. de la Rosa, Joseph W. Yoo, Aron Walsh, Brent C. Melot, Smaranda C. Marinescu","doi":"10.1021/jacs.4c13151","DOIUrl":null,"url":null,"abstract":"The authors retract this Article (10.1021/jacs.7b05742) following concerns raised about the temperature-dependent resistivity data. The authors recharacterized the samples and determined that the anomalous temperature-dependent maxima reported were not due to metallic conductivity. Instead, it was found that ohmic contact was lost during cooling. This resulted in a significant reduction to the current passing between the electrodes, which could not be detected using the equipment available at the time. The authors note that the density functional theory (DFT) calculations, synthetic studies, synchrotron X-ray powder diffraction, modeling, Brunauer–Emmett–Teller (BET) measurements, scanning electron microscopy and atomic force microscopy, and magnetic susceptibility measurements stand on their own merit. However, due to the misinterpretation of the conductivity data, the findings of the work are incorrect, and thus the paper is being retracted. The original Article was published on July 13, 2017, and retracted on April 7, 2025. This article has not yet been cited by other publications.","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"38 1","pages":""},"PeriodicalIF":15.6000,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Retraction of “Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal–Organic Framework”\",\"authors\":\"Andrew J. Clough, Jonathan M. Skelton, Courtney A. Downes, Ashley A. de la Rosa, Joseph W. Yoo, Aron Walsh, Brent C. Melot, Smaranda C. Marinescu\",\"doi\":\"10.1021/jacs.4c13151\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The authors retract this Article (10.1021/jacs.7b05742) following concerns raised about the temperature-dependent resistivity data. The authors recharacterized the samples and determined that the anomalous temperature-dependent maxima reported were not due to metallic conductivity. Instead, it was found that ohmic contact was lost during cooling. This resulted in a significant reduction to the current passing between the electrodes, which could not be detected using the equipment available at the time. The authors note that the density functional theory (DFT) calculations, synthetic studies, synchrotron X-ray powder diffraction, modeling, Brunauer–Emmett–Teller (BET) measurements, scanning electron microscopy and atomic force microscopy, and magnetic susceptibility measurements stand on their own merit. However, due to the misinterpretation of the conductivity data, the findings of the work are incorrect, and thus the paper is being retracted. The original Article was published on July 13, 2017, and retracted on April 7, 2025. This article has not yet been cited by other publications.\",\"PeriodicalId\":49,\"journal\":{\"name\":\"Journal of the American Chemical Society\",\"volume\":\"38 1\",\"pages\":\"\"},\"PeriodicalIF\":15.6000,\"publicationDate\":\"2025-04-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the American Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/jacs.4c13151\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/jacs.4c13151","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

由于对温度相关电阻率数据的担忧,作者撤回了这篇文章(10.1021/ jax .7b05742)。作者重新表征了样品,并确定报告的异常温度依赖性最大值不是由于金属导电性。相反,人们发现在冷却过程中欧姆接触丢失了。这大大减少了通过电极之间的电流,这是当时可用设备无法检测到的。作者指出,密度泛函理论(DFT)计算、合成研究、同步加速器x射线粉末衍射、建模、布鲁诺尔-埃米特-泰勒(BET)测量、扫描电子显微镜和原子力显微镜以及磁化率测量都有其自身的优点。然而,由于对电导率数据的误解,这项工作的发现是不正确的,因此该论文被撤回。原文发表于2017年7月13日,并于2025年4月7日撤回。这篇文章尚未被其他出版物引用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Retraction of “Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal–Organic Framework”
The authors retract this Article (10.1021/jacs.7b05742) following concerns raised about the temperature-dependent resistivity data. The authors recharacterized the samples and determined that the anomalous temperature-dependent maxima reported were not due to metallic conductivity. Instead, it was found that ohmic contact was lost during cooling. This resulted in a significant reduction to the current passing between the electrodes, which could not be detected using the equipment available at the time. The authors note that the density functional theory (DFT) calculations, synthetic studies, synchrotron X-ray powder diffraction, modeling, Brunauer–Emmett–Teller (BET) measurements, scanning electron microscopy and atomic force microscopy, and magnetic susceptibility measurements stand on their own merit. However, due to the misinterpretation of the conductivity data, the findings of the work are incorrect, and thus the paper is being retracted. The original Article was published on July 13, 2017, and retracted on April 7, 2025. This article has not yet been cited by other publications.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
24.40
自引率
6.00%
发文量
2398
审稿时长
1.6 months
期刊介绍: The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信