Yuwei Ning , Fali Liu , Xiaoma Tao , Guanglong Xu , Hongmei Chen , Yifang Ouyang , Yong Du
{"title":"BCC富Ti Ti- zr - ta体系的扩散系数和力学性能研究","authors":"Yuwei Ning , Fali Liu , Xiaoma Tao , Guanglong Xu , Hongmei Chen , Yifang Ouyang , Yong Du","doi":"10.1016/j.calphad.2025.102827","DOIUrl":null,"url":null,"abstract":"<div><div>In this work, a combination of diffusion couple technique and nanoindentation were employed to investigate the diffusion behaviors and mechanical properties of Ti-Zr-Ta alloys annealed at 1373 K for 26 h. The experiments focused on Ti-rich body-centered cubic (BCC) Ti-Zr-Ta ternary alloys. Diffusion coefficients were determined using the Whittle-Green and generalized Hall methods, while nanoindentation was utilized to characterize Young's modulus and hardness of the alloys. The results indicate that the diffusion rate of Zr is considerably higher than that of Ta, and the diffusion rate of both elements exhibits a strong dependence on concentration. The mechanical testing results demonstrate a significant increase in the hardness and Young's modulus of the alloy as the Ta content increases. In contrast, the Zr content shows a relatively limited effect on hardness and Young's modulus. These results provide an essential reference for further optimization of the microstructure and mechanical properties of Ti-Zr-Ta alloys at elevated temperatures.</div></div>","PeriodicalId":9436,"journal":{"name":"Calphad-computer Coupling of Phase Diagrams and Thermochemistry","volume":"89 ","pages":""},"PeriodicalIF":1.9000,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation of diffusivities and mechanical properties in BCC Ti rich Ti-Zr-Ta system\",\"authors\":\"Yuwei Ning , Fali Liu , Xiaoma Tao , Guanglong Xu , Hongmei Chen , Yifang Ouyang , Yong Du\",\"doi\":\"10.1016/j.calphad.2025.102827\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this work, a combination of diffusion couple technique and nanoindentation were employed to investigate the diffusion behaviors and mechanical properties of Ti-Zr-Ta alloys annealed at 1373 K for 26 h. The experiments focused on Ti-rich body-centered cubic (BCC) Ti-Zr-Ta ternary alloys. Diffusion coefficients were determined using the Whittle-Green and generalized Hall methods, while nanoindentation was utilized to characterize Young's modulus and hardness of the alloys. The results indicate that the diffusion rate of Zr is considerably higher than that of Ta, and the diffusion rate of both elements exhibits a strong dependence on concentration. The mechanical testing results demonstrate a significant increase in the hardness and Young's modulus of the alloy as the Ta content increases. In contrast, the Zr content shows a relatively limited effect on hardness and Young's modulus. These results provide an essential reference for further optimization of the microstructure and mechanical properties of Ti-Zr-Ta alloys at elevated temperatures.</div></div>\",\"PeriodicalId\":9436,\"journal\":{\"name\":\"Calphad-computer Coupling of Phase Diagrams and Thermochemistry\",\"volume\":\"89 \",\"pages\":\"\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2025-04-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Calphad-computer Coupling of Phase Diagrams and Thermochemistry\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0364591625000306\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Calphad-computer Coupling of Phase Diagrams and Thermochemistry","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0364591625000306","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Investigation of diffusivities and mechanical properties in BCC Ti rich Ti-Zr-Ta system
In this work, a combination of diffusion couple technique and nanoindentation were employed to investigate the diffusion behaviors and mechanical properties of Ti-Zr-Ta alloys annealed at 1373 K for 26 h. The experiments focused on Ti-rich body-centered cubic (BCC) Ti-Zr-Ta ternary alloys. Diffusion coefficients were determined using the Whittle-Green and generalized Hall methods, while nanoindentation was utilized to characterize Young's modulus and hardness of the alloys. The results indicate that the diffusion rate of Zr is considerably higher than that of Ta, and the diffusion rate of both elements exhibits a strong dependence on concentration. The mechanical testing results demonstrate a significant increase in the hardness and Young's modulus of the alloy as the Ta content increases. In contrast, the Zr content shows a relatively limited effect on hardness and Young's modulus. These results provide an essential reference for further optimization of the microstructure and mechanical properties of Ti-Zr-Ta alloys at elevated temperatures.
期刊介绍:
The design of industrial processes requires reliable thermodynamic data. CALPHAD (Computer Coupling of Phase Diagrams and Thermochemistry) aims to promote computational thermodynamics through development of models to represent thermodynamic properties for various phases which permit prediction of properties of multicomponent systems from those of binary and ternary subsystems, critical assessment of data and their incorporation into self-consistent databases, development of software to optimize and derive thermodynamic parameters and the development and use of databanks for calculations to improve understanding of various industrial and technological processes. This work is disseminated through the CALPHAD journal and its annual conference.