Bis ((2-meth-oxy-phen-yl) di-phenyl-phosphane -κP] (nitrito -κ2 O, O ')银(我)

IUCrData Pub Date : 2025-03-01 DOI:10.1107/S2414314625001932

Frederick P. Malan , Kariska Potgieter , Reinout Meijboom

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引用次数: 0

摘要

报道了一种二苯基银-2-甲基-氧基苯基膦亚硝酸盐配合物的合成及其单晶结构描述。本文描述了标题AgI配合物[Ag(NO2)(C19H17OP)2]的分子结构，其中AgI原子在O2P2供体集中以双齿模式作为亚硝基阴离子配位存在明显的扭曲的四面体配位环境。P-Ag-P有一个相当大的角度[129.126（16）°]。O-Ag-O螯合角为= 50.38(6)°，P-Ag-O螯合角为99.51(5)~ 118.45(6)°。在晶体中，C-H⋯O相互作用是明显的。下载：下载高清图片（432KB）下载：下载全尺寸图片

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Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I)

The synthesis and single-crystal structure description of a silver(I) diphenyl-2-methoxyphenylphosphine nitrite complex is described.

The molecular structure of the title Ag^I complex, [Ag(NO₂)(C₁₉H₁₇OP)₂], is described, where a distorted tetrahedral coordination environment for the Ag^I atom is apparent within a O₂P₂ donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P—Ag—P [129.126 (16)°] is noted. The O—Ag—O chelate angle is = 50.38 (6)° and the P—Ag—O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C—H⋯O interactions are evident.

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IUCrData

CiteScore

0.30

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0.00%

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