易于接近的β-锗取代胺硼烷与增强的荧光效率

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-03-26 DOI:10.1021/acs.orglett.5c0043510.1021/acs.orglett.5c00435

Zi-Long An, Ao-Xiang Yu, Dun-Xu Cao and Bin Xiao*,

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引用次数: 0

摘要

2-吡啶基取代炔基germanes与9-硼比环壬烷（9-BBN）硼氢化反应生成一系列含N-B配位的乙烯基硼烷。与它们对应的炔基硅烷不同，这个反应涉及到胚芽基的迁移。与先前报道的α-取代类似物相比，这些分子内仅在β-位置取代的胺硼烷表现出明显强的蓝色荧光，并显示出更高的荧光效率。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Readily Accessible β-Ge-Substituted Amine-Boranes with Enhanced Fluorescence Efficiency

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Readily Accessible β-Ge-Substituted Amine-Boranes with Enhanced Fluorescence Efficiency

The hydroboration of 2-pyridyl-substituted alkynylgermanes with 9-borabicyclo[3.3.1]nonane (9-BBN) produces a series of vinylboranes containing N–B coordination. In contrast to their alkynylsilane counterparts, this reaction involves migration of the germyl group. These intramolecular amine-boranes with substitution exclusively at the β-position exhibit significantly strong blue fluorescence and show enhanced fluorescence efficiency compared to previously reported analogues with α-substitution.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.